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SDBS-assisted preparation of novel polyaniline planar-structure: Morphology, mechanism and hydrophobicity
Fan, Haosen1,2; Wang, Hao1; Guo, Jing1; Zhao, Ning1; Xu, Jian1
刊名JOURNAL OF COLLOID AND INTERFACE SCIENCE
2014-01-15
卷号414页码:46-49
关键词Hydrophobicity Leaf-like Micro/nanostructure Polyaniline Surfactant
ISSN号0021-9797
DOI10.1016/j.jcis.2013.09.042
英文摘要Leaf-like hierarchical polyaniline (PANI) structure with interlaced nanofibers on the surface was prepared by chemical oxidation polymerization of aniline assisted by sodium dodecyl benzene sulfonate (SDBS). The chemical structure and the composition of the leaf-like PANI obtained were characterized by FTIR, UV-vis, XRD and XPS. In order to investigate the formation mechanism of such micro/nanostructures, some micro/nanostructures of PANI polymerized at different polymerization times were synthesized and observed for comparison. The results show that the PANI micro/nanostructures originate from PANI microleaves due to SDBS as soft template, which then covered with interlaced nanofibers on the surface. The leaf-like PANI micro/nanostructures exhibit good hydrophobic property with a water contact angle of 134.3 degrees resulted from the hydrophobic long dodecyl groups of SDBS dopant. Crown Copyright (C) 2013 Published by Elsevier Inc. All rights reserved.
语种英语
出版者ACADEMIC PRESS INC ELSEVIER SCIENCE
WOS记录号WOS:000327292900007
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/51021]  
专题中国科学院化学研究所
通讯作者Zhao, Ning
作者单位1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Lab Polymer Phys & Chem, Beijing 100190, Peoples R China
2.Peking Univ, Sch Adv Mat, Shenzhen Grad Sch, Shenzhen 518055, Peoples R China
推荐引用方式
GB/T 7714
Fan, Haosen,Wang, Hao,Guo, Jing,et al. SDBS-assisted preparation of novel polyaniline planar-structure: Morphology, mechanism and hydrophobicity[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE,2014,414:46-49.
APA Fan, Haosen,Wang, Hao,Guo, Jing,Zhao, Ning,&Xu, Jian.(2014).SDBS-assisted preparation of novel polyaniline planar-structure: Morphology, mechanism and hydrophobicity.JOURNAL OF COLLOID AND INTERFACE SCIENCE,414,46-49.
MLA Fan, Haosen,et al."SDBS-assisted preparation of novel polyaniline planar-structure: Morphology, mechanism and hydrophobicity".JOURNAL OF COLLOID AND INTERFACE SCIENCE 414(2014):46-49.
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