Amine-accelerated manganese-catalyzed aromatic C-H conjugate addition to alpha,beta-unsaturated carbonyls | |
Zhou, Bingwei1; Ma, Pengchen2; Chen, Hui2; Wang, Congyang1 | |
刊名 | CHEMICAL COMMUNICATIONS |
2014 | |
卷号 | 50期号:93页码:14558-14561 |
ISSN号 | 1359-7345 |
DOI | 10.1039/c4cc07598f |
英文摘要 | Since 1987, the stoichiometric two-step C-H conjugate addition reactions have been developed. Herein we describe the first manganese-catalyzed one-step direct aromatic C-H conjugate addition to alpha,beta-unsaturated carbonyls, which is accelerated by a catalytic amount of dicyclohexylamine. Experimental and computational studies substantiated the validity of the proposed catalytic cycle. |
语种 | 英语 |
出版者 | ROYAL SOC CHEMISTRY |
WOS记录号 | WOS:000344459400019 |
内容类型 | 期刊论文 |
源URL | [http://ir.iccas.ac.cn/handle/121111/50331] |
专题 | 中国科学院化学研究所 |
通讯作者 | Chen, Hui |
作者单位 | 1.Chinese Acad Sci, Inst Chem, CAS Key Lab Mol Recognit & Funct, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Chem, CAS Key Lab Photochem, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Zhou, Bingwei,Ma, Pengchen,Chen, Hui,et al. Amine-accelerated manganese-catalyzed aromatic C-H conjugate addition to alpha,beta-unsaturated carbonyls[J]. CHEMICAL COMMUNICATIONS,2014,50(93):14558-14561. |
APA | Zhou, Bingwei,Ma, Pengchen,Chen, Hui,&Wang, Congyang.(2014).Amine-accelerated manganese-catalyzed aromatic C-H conjugate addition to alpha,beta-unsaturated carbonyls.CHEMICAL COMMUNICATIONS,50(93),14558-14561. |
MLA | Zhou, Bingwei,et al."Amine-accelerated manganese-catalyzed aromatic C-H conjugate addition to alpha,beta-unsaturated carbonyls".CHEMICAL COMMUNICATIONS 50.93(2014):14558-14561. |
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