A Nanosized {Ag@Ag-12} "Molecular Windmill" Templated by Polyoxometalates Anions

doi:10.1021/ic501657p

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	A Nanosized {Ag@Ag-12} "Molecular Windmill" Templated by Polyoxometalates Anions
	Wang, Lei 1; Yang, Weiting 1; Zhu, Wei 1; Guan, Xingang 2; Xie, Zhigang 2; Sun, Zhong-Ming 1
刊名	INORGANIC CHEMISTRY
	2014-11-03
卷号	53 期号:21 页码:11584-11588
ISSN号	0020-1669
DOI	10.1021/ic501657p
英文摘要	Reaction of multidentate 5-(4-imidazol-1-yl-phenyl)-2H-tetrazole (L) ligand with Ag(I) ions in the existence of H(3)PW(1)2O(4)0 as anionic template under hydrothermal conditions results in tridecanuclear silver cluster-polyoxometalates hybrid: {Ag13L12}{PW12O40}(4).30H(2)O (1). X-ray single crystal diffraction analysis indicates that the main structural feature of 1 is a nanosized molecular windmill-shaped polynuclear Ag cluster with intriguing {M@M-12}-type cuboctahedral topology. The as-synthesized compound exhibits effective photocatalytic activity in the photodegradation of Rhodamine-B (RhB) and antibacterial activity against Escherichia coli, respectively.
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000344307400027
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/50027]
专题	中国科学院化学研究所
通讯作者	Sun, Zhong-Ming
作者单位	1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Jilin, Peoples R China 2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Jilin, Peoples R China
推荐引用方式 GB/T 7714	Wang, Lei,Yang, Weiting,Zhu, Wei,et al. A Nanosized {Ag@Ag-12} "Molecular Windmill" Templated by Polyoxometalates Anions[J]. INORGANIC CHEMISTRY,2014,53(21):11584-11588.
APA	Wang, Lei,Yang, Weiting,Zhu, Wei,Guan, Xingang,Xie, Zhigang,&Sun, Zhong-Ming.(2014).A Nanosized {Ag@Ag-12} "Molecular Windmill" Templated by Polyoxometalates Anions.INORGANIC CHEMISTRY,53(21),11584-11588.
MLA	Wang, Lei,et al."A Nanosized {Ag@Ag-12} "Molecular Windmill" Templated by Polyoxometalates Anions".INORGANIC CHEMISTRY 53.21(2014):11584-11588.