Synthesis, structure and magnetic property of a new nickel (II) 1,4-benzenedicarboxylate

doi:10.1016/j.molstruc.2011.12.005

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	Synthesis, structure and magnetic property of a new nickel (II) 1,4-benzenedicarboxylate
	Hua, Wei 1; Fu, Ying 1; Su, Jie 1; Yang, Sihai 2; Li, Guobao 1; Liao, Fuhui 1; Lin, Jianhua 1
刊名	JOURNAL OF MOLECULAR STRUCTURE
	2012-02-29
卷号	1010 页码:184-189
关键词	Metal Organic Framework Hydrothermal Synthesis Structure 2d Layer Nickel (Ii) 1 4-benzenedicarboxylate (H2bdc)
ISSN号	0022-2860
DOI	10.1016/j.molstruc.2011.12.005
英文摘要	Ni-2(H2O)(en)(2)(BDC)(2) (1) (en = ethylenediamine, BDC = 1,4-benzenedicarboxylate), has been synthesized hydrothermally. 1 Crystallizes in orthorhombic space group Fddd with a = 10.623(2) angstrom, b = 21.104(4) angstrom, and c = 42.829(9) angstrom. is constructed from stacked neutral layers, [Ni-2(H2O)(en)(2)(BDC)(2)](n). Ni ions in the structure coordinate to four oxygen atoms and two nitrogen atoms to form NiO4N2 octahedra and two NiO4N2 octahedra connect to each other with a common oxygen atom to form a Ni2O7N4 dimer. Magnetic measurement shows that the dominant magnetic exchange interactions of 1 are ferromagnetic in origin. TG-DSC studies show that 1 is stable up to 300 degrees C. (C) 2011 Elsevier B.V. All rights reserved.
语种	英语
出版者	ELSEVIER SCIENCE BV
WOS记录号	WOS:000301606200027
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/49481]
专题	中国科学院化学研究所
通讯作者	Li, Guobao
作者单位	1.Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, BNLMS, Beijing 100871, Peoples R China 2.Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England
推荐引用方式 GB/T 7714	Hua, Wei,Fu, Ying,Su, Jie,et al. Synthesis, structure and magnetic property of a new nickel (II) 1,4-benzenedicarboxylate[J]. JOURNAL OF MOLECULAR STRUCTURE,2012,1010:184-189.
APA	Hua, Wei.,Fu, Ying.,Su, Jie.,Yang, Sihai.,Li, Guobao.,...&Lin, Jianhua.(2012).Synthesis, structure and magnetic property of a new nickel (II) 1,4-benzenedicarboxylate.JOURNAL OF MOLECULAR STRUCTURE,1010,184-189.
MLA	Hua, Wei,et al."Synthesis, structure and magnetic property of a new nickel (II) 1,4-benzenedicarboxylate".JOURNAL OF MOLECULAR STRUCTURE 1010(2012):184-189.