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Enhanced electrocatalytic performance for methanol oxidation of Pt nanoparticles on Mn3O(4)-modified multi-walled carbon nanotubes
Yang, Xiulin1,2; Wang, Xueyun1,2; Zhang, Guoqiang1,2; Zheng, Junpeng1,2; Wang, Taishan1,2; Liu, Xianzong1; Shu, Chunying1; Jiang, Li1; Wang, Chunru1
刊名INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
2012-08-01
卷号37期号:15页码:11167-11175
关键词Pt Nanoparticles Mn3o4 Multi-walled Carbon Nanotubes Electrocatalysis Fuel Cells
ISSN号0360-3199
DOI10.1016/j.ijhydene.2012.04.153
英文摘要We report the preparation of well-dispersed Pt nanoparticles depositing on Mn3O4-modified multi-walled carbon nanotubes (Mn3O4-MWCNTs) that can be taken as high performance catalyst in methanol electro-oxidation. Various spectrometry techniques such as FT-IR, Raman, XRD, TEM and XPS measurements were performed, revealing that the Pt nanoparticles were highly dispersed on the surface of Mn3O4-modified MWCNTs with a narrow size distribution between 1.7 nm and 3.9 nm. Compared the Pt/MWCNT catalyst without Mn3O4 modification, the Pt/Mn3O4-MWCNT composite catalyst not only shows relative large electrochemical active surface area (EAS), high catalyzing activity toward methanol electro-oxidation, but also exhibits very high stability with apparent anti-poisoning tolerance to the incomplete oxidized species during methanol oxidation. Copyright (c) 2012, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
语种英语
出版者PERGAMON-ELSEVIER SCIENCE LTD
WOS记录号WOS:000307600700020
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/48625]  
专题中国科学院化学研究所
通讯作者Jiang, Li
作者单位1.Chinese Acad Sci, Inst Chem, Key Lab Mol Nanostruct & Nanotechnol, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
Yang, Xiulin,Wang, Xueyun,Zhang, Guoqiang,et al. Enhanced electrocatalytic performance for methanol oxidation of Pt nanoparticles on Mn3O(4)-modified multi-walled carbon nanotubes[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2012,37(15):11167-11175.
APA Yang, Xiulin.,Wang, Xueyun.,Zhang, Guoqiang.,Zheng, Junpeng.,Wang, Taishan.,...&Wang, Chunru.(2012).Enhanced electrocatalytic performance for methanol oxidation of Pt nanoparticles on Mn3O(4)-modified multi-walled carbon nanotubes.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,37(15),11167-11175.
MLA Yang, Xiulin,et al."Enhanced electrocatalytic performance for methanol oxidation of Pt nanoparticles on Mn3O(4)-modified multi-walled carbon nanotubes".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 37.15(2012):11167-11175.
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