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White electroluminescent single-polymer achieved by incorporating three polyfluorene blue arms into a star-shaped orange core
Chen, Lei1,2; Li, Pengcheng1,2; Tong, Hui1; Xie, Zhiyuan1; Wang, Lixiang1; Jing, Xiabin1; Wang, Fosong1
刊名JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
2012-07-15
卷号50期号:14页码:2854-2862
关键词Benzothiadiazole Branched Conjugated Polymers Light-emitting Diodes White Electroluminescence
ISSN号0887-624X
DOI10.1002/pola.26061
英文摘要A series of star-like dopant/host single-polymer systems with a D-A type star-shaped orange core and three blue polyfluorene arms were designed and synthesized. Through tuning the doping concentration of the orange core and thermal annealing treatment of white polymer light-emitting diodes based on them, highly efficient white electroluminescence has been achieved. A typical single-layer device (ITO/PEDOT:PSS/polymer/Ca/Al) realized pure white emission with a luminous efficiency of 16.62 cd A-1, an external quantum efficiency of 6.28% and CIE coordinates of (0.33, 0.36) for S-WP-002TPB3 containing 0.02 mol % orange core. The high efficiency of the devices could be mainly attributed to the suppressed concentration quenching of the dopant units, more efficient energy transfer from polymer host to orange dopant and thermal annealing-induced a-phase polyfluorene (PF) self-dopant in amorphous PF host. (C) 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012
语种英语
出版者WILEY-BLACKWELL
WOS记录号WOS:000304813300012
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/48065]  
专题中国科学院化学研究所
通讯作者Wang, Lixiang
作者单位1.Acad Sinica, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
Chen, Lei,Li, Pengcheng,Tong, Hui,et al. White electroluminescent single-polymer achieved by incorporating three polyfluorene blue arms into a star-shaped orange core[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,2012,50(14):2854-2862.
APA Chen, Lei.,Li, Pengcheng.,Tong, Hui.,Xie, Zhiyuan.,Wang, Lixiang.,...&Wang, Fosong.(2012).White electroluminescent single-polymer achieved by incorporating three polyfluorene blue arms into a star-shaped orange core.JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,50(14),2854-2862.
MLA Chen, Lei,et al."White electroluminescent single-polymer achieved by incorporating three polyfluorene blue arms into a star-shaped orange core".JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 50.14(2012):2854-2862.
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