Synthesis and Electronic Structure of Boron-Graphdiyne with an sp-Hybridized Carbon Skeleton and Its Application in Sodium Storage

doi:10.1002/anie.201800453

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	Synthesis and Electronic Structure of Boron-Graphdiyne with an sp-Hybridized Carbon Skeleton and Its Application in Sodium Storage
	Wang, Ning 1; Li, Xiaodong 1,2; Tu, Zeyi 2,3; Zhao, Fuhua 1; He, Jianjiang 1; Guan, Zhaoyong 1; Huang, Changshui 1; Yi, Yuanping 3; Li, Yuliang 3
刊名	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
	2018-04-03
卷号	57 期号:15 页码:3968-3973
关键词	Boron Carbon Materials Electrochemistry Energy Storage Graphdiyne
ISSN号	1433-7851
DOI	10.1002/anie.201800453
英文摘要	Boron-graphdiyne (BGDY), which has a unique pi-conjugated structure comprising an sp-hybridized carbon skeleton and evenlydistributed boron heteroatoms in a well-organized 2D molecular plane, is prepared through a bottom-up synthetic strategy. Excellent conductivity, a relatively low band gap and a packing mode of the planar BGDY are observed. Notably, the unusual bonding environment of the all sp-carbon framework and the electron-deficient boron centers generates affinity to metal atoms, and thus provides extra binding sites. Furthermore, the expanded molecule pores of the BGDY molecular plane can also facilitate the transfer of metal ions in the perpendicular direction. The practical effect of the all sp-carbon structure and boron heteroatoms on the properties of BGDY are demonstrated in its performance as the anode in sodium-ion batteries.
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000428350200017
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/46123]
专题	中国科学院化学研究所
通讯作者	Huang, Changshui; Li, Yuliang
作者单位	1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, 189 Songling Rd, Qingdao 266101, Peoples R China 2.Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China 3.Chinese Acad Sci, CAS Key Lab Organ Solids, BNLMS, Inst Chem, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Wang, Ning,Li, Xiaodong,Tu, Zeyi,et al. Synthesis and Electronic Structure of Boron-Graphdiyne with an sp-Hybridized Carbon Skeleton and Its Application in Sodium Storage[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2018,57(15):3968-3973.
APA	Wang, Ning.,Li, Xiaodong.,Tu, Zeyi.,Zhao, Fuhua.,He, Jianjiang.,...&Li, Yuliang.(2018).Synthesis and Electronic Structure of Boron-Graphdiyne with an sp-Hybridized Carbon Skeleton and Its Application in Sodium Storage.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,57(15),3968-3973.
MLA	Wang, Ning,et al."Synthesis and Electronic Structure of Boron-Graphdiyne with an sp-Hybridized Carbon Skeleton and Its Application in Sodium Storage".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 57.15(2018):3968-3973.