Applications of Helicenes and Their Derivatives in Asymmetric Catalysis | |
Fang Lei1,2; Lin Weibin1,2; Shen Yun1; Chen Chuanfeng1,2 | |
刊名 | CHINESE JOURNAL OF ORGANIC CHEMISTRY |
2018-03-25 | |
卷号 | 38期号:3页码:541-554 |
关键词 | Helicene Asymmetric Catalysis Chiral Induction Helical Ligand Organocatalyst |
ISSN号 | 0253-2786 |
DOI | 10.6023/cjoc201710028 |
英文摘要 | Helicenes are a kind of pi-conjugated helical compounds which are consisted of ortho-fused benzene or other aromatic rings. Compared to other kinds of chiral catalysts, studies on helicene-based catalysts with helical chirality showed late start and lagging development. However, since helicene molecules exhibit structural rigidity, thermal stability, easily functionalization, and excellent chiral environment for asymmetric catalysis by continuous elaborate curve in three-dimensional space, investigation on the synthesis of helicene-based chiral catalysts and their applications in asymmetric catalysis have attracted increasing interest in recent years. According to the different roles of the helicenes played in the asymmetric catalysis, the helicene-based catalysts can be classified into chiral inducers, helically chiral ligands and helical organocatalysts, and their applications in asymmetric catalysis will be focused on in this review, respectively. |
语种 | 英语 |
出版者 | SCIENCE PRESS |
WOS记录号 | WOS:000430319000001 |
内容类型 | 期刊论文 |
源URL | [http://ir.iccas.ac.cn/handle/121111/45949] |
专题 | 中国科学院化学研究所 |
通讯作者 | Chen Chuanfeng |
作者单位 | 1.Chinese Acad Sci, Key Lab Mol Recognit & Funct, Inst Chem, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Fang Lei,Lin Weibin,Shen Yun,et al. Applications of Helicenes and Their Derivatives in Asymmetric Catalysis[J]. CHINESE JOURNAL OF ORGANIC CHEMISTRY,2018,38(3):541-554. |
APA | Fang Lei,Lin Weibin,Shen Yun,&Chen Chuanfeng.(2018).Applications of Helicenes and Their Derivatives in Asymmetric Catalysis.CHINESE JOURNAL OF ORGANIC CHEMISTRY,38(3),541-554. |
MLA | Fang Lei,et al."Applications of Helicenes and Their Derivatives in Asymmetric Catalysis".CHINESE JOURNAL OF ORGANIC CHEMISTRY 38.3(2018):541-554. |
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