Dramatic differences in the fluorescence of AIEgen-doped micro- and macrophase separated systems

doi:10.1039/c7tc04771a

CORC > 化学研究所 > 中国科学院化学研究所

	Dramatic differences in the fluorescence of AIEgen-doped micro- and macrophase separated systems
	Song, Zehua 1; Lv, Xiaolin 2; Gao, Longcheng 1; Jiang, Lei 1,3
刊名	JOURNAL OF MATERIALS CHEMISTRY C
	2018-01-07
卷号	6 期号:1 页码:171-177
ISSN号	2050-7526
DOI	10.1039/c7tc04771a
英文摘要	A block copolymer (BCP) and a polymer blend containing small amounts of fluorogenic molecules with aggregation-induced emission (AIE) characteristics exhibited dramatic differences in the fluorescence properties. In particular, AIEgens with different polarities were doped in BCP polystyrene-b-polylactide (PS-b-PLA) and the PS/PLA blend. For the BCP, whether the AIEgens were selectively located in one phase or not, the intramolecular motions of the phenyl rings in AIEgens were affected by both the PS and PLA segment motions, due to the covalent bonds between the constitutive blocks. Therefore, the fluorescence was affected by the segment movements of PS and PLA. In contrast, the AIEgen-doped polymer blend exhibited location dependent fluorescence. The fluorescence was affected by the segment movements where the AIEgens were located, because there were no connections between the PS and PLA chains. This visualization method will provide new insights into monitoring the chain motions of macromolecules with more complex structures.
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000418620900019
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/45361]
专题	中国科学院化学研究所
通讯作者	Gao, Longcheng
作者单位	1.Beihang Univ, Sch Chem & Environm, Key Lab Beijing Energy, Minist Educ,Lab Bioinspired Smart Interfacial Sci, Beijing 100191, Peoples R China 2.Peking Univ, Beijing Natl Lab Mol Sci, Key Lab Polymer Chem & Phys, Minist Educ,Coll Chem & Mol Engn, Beijing 100871, Peoples R China 3.Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Bioinspired Mat & Interfacial Sci, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Song, Zehua,Lv, Xiaolin,Gao, Longcheng,et al. Dramatic differences in the fluorescence of AIEgen-doped micro- and macrophase separated systems[J]. JOURNAL OF MATERIALS CHEMISTRY C,2018,6(1):171-177.
APA	Song, Zehua,Lv, Xiaolin,Gao, Longcheng,&Jiang, Lei.(2018).Dramatic differences in the fluorescence of AIEgen-doped micro- and macrophase separated systems.JOURNAL OF MATERIALS CHEMISTRY C,6(1),171-177.
MLA	Song, Zehua,et al."Dramatic differences in the fluorescence of AIEgen-doped micro- and macrophase separated systems".JOURNAL OF MATERIALS CHEMISTRY C 6.1(2018):171-177.