A neutral auxiliary ligand enhanced dysprosium(iii) single molecule magnet

doi:10.1039/c8dt01102h

CORC > 化学研究所 > 中国科学院化学研究所

	A neutral auxiliary ligand enhanced dysprosium(iii) single molecule magnet
	Chen, Xiao-Xiang 1; Ma, Fang 2,3; Xu, Mei-Xing 1; Bi, Jin-Cheng 1; Sun, Hao-Ling 2,3; Wang, Bing-Wu 1; Gao, Song 1
刊名	DALTON TRANSACTIONS
	2018-06-14
卷号	47 期号:22 页码:7395-7398
ISSN号	1477-9226
DOI	10.1039/c8dt01102h
英文摘要	An approximately equatorial three-coordinated dysprosium(iii) complex DyL2[N(SiMe3)(2)] (L = bis(2-(2,5-dimethyl-1H-pyrrol-1-yl)ethyl)amine) with an additional neutral auxiliary pyrrole ligand was synthesised and structurally characterized. The magnetic property measurement shows that it is an equatorial charge distributed field-induced single-molecule magnet. Ab initio calculations reveal that the neutral pyrrole ligand plays an important role in stabilizing the ground doublet and thus enhancing the magnetic anisotropy.
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000434313900002
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/42781]
专题	中国科学院化学研究所
通讯作者	Sun, Hao-Ling; Wang, Bing-Wu; Gao, Song
作者单位	1.Peking Univ, Beijing Natl Lab Mol Sci, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China 2.Beijing Normal Univ, Dept Chem, Beijing 100875, Peoples R China 3.Beijing Normal Univ, Beijing Key Lab Energy Convers & Storage Mat, Beijing 100875, Peoples R China
推荐引用方式 GB/T 7714	Chen, Xiao-Xiang,Ma, Fang,Xu, Mei-Xing,et al. A neutral auxiliary ligand enhanced dysprosium(iii) single molecule magnet[J]. DALTON TRANSACTIONS,2018,47(22):7395-7398.
APA	Chen, Xiao-Xiang.,Ma, Fang.,Xu, Mei-Xing.,Bi, Jin-Cheng.,Sun, Hao-Ling.,...&Gao, Song.(2018).A neutral auxiliary ligand enhanced dysprosium(iii) single molecule magnet.DALTON TRANSACTIONS,47(22),7395-7398.
MLA	Chen, Xiao-Xiang,et al."A neutral auxiliary ligand enhanced dysprosium(iii) single molecule magnet".DALTON TRANSACTIONS 47.22(2018):7395-7398.