F-Substituted oligothiophenes serve as nonfullerene acceptors in polymer solar cells with open-circuit voltages >1 v | |
Duan, Tainan1,2; Babics, Maxime2; Seitkhan, Akmaral2; Firdaus, Yuliar2; Liang, Ru-Ze2; Cruciani, Federico2; Liu, Shengjian2; Lopatin, Sergei3; Beaujuge, Pierre M.2 | |
刊名 | Journal of Materials Chemistry A |
2018 | |
卷号 | 6期号:20页码:9368-9372 |
ISSN号 | 20507488 |
DOI | 10.1039/c8ta02781a |
英文摘要 | We report on a set of two analogous, F-substituted oligothiophene derivatives (D5T6F-M and D7T8F-M), in which systematic fluorination at the thienyl moieties is shown to induce a sufficient increase in electron affinity (EA; i.e. suppressed LUMO level) and in ionization potential (IP; i.e. deeper HOMO) to (i) impart the molecules with electron-accepting and -transporting characteristics, and (ii) yield high open-circuit voltages >1 V in BHJ solar cells when combined with a low-bandgap polymer donor (PCE10) commonly used with fullerenes. The nonfullerene BHJ devices with the SM acceptor D5T6F-M achieve power conversion efficiencies (PCEs) of up to ca. 4.5% (vs. ca. 2% for D7T8F-M-based devices). Our study shows that -F substitutions in SM systems-otherwise used as donors-is an effective approach in the design of nonfullerene acceptors for efficient BHJ solar cells with polymer donors. © 2018 The Royal Society of Chemistry. |
电子版国际标准刊号 | 20507496 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://119.78.100.138/handle/2HOD01W0/7998] |
专题 | 中国科学院重庆绿色智能技术研究院 |
作者单位 | 1.Chongqing Institute of Green and Intelligent Technology, Chinese Academy of Sciences, Chongqing; 401122, China; 2.Physical Science and Engineering Division, KAUST Solar Center (KSC), King Abdullah University of Science and Technology (KAUST), Thuwal; 23955-6900, Saudi Arabia; 3.King Abdullah University of Science and Technology (KAUST), Core Labs, Thuwal; 23955-6900, Saudi Arabia |
推荐引用方式 GB/T 7714 | Duan, Tainan,Babics, Maxime,Seitkhan, Akmaral,et al. F-Substituted oligothiophenes serve as nonfullerene acceptors in polymer solar cells with open-circuit voltages >1 v[J]. Journal of Materials Chemistry A,2018,6(20):9368-9372. |
APA | Duan, Tainan.,Babics, Maxime.,Seitkhan, Akmaral.,Firdaus, Yuliar.,Liang, Ru-Ze.,...&Beaujuge, Pierre M..(2018).F-Substituted oligothiophenes serve as nonfullerene acceptors in polymer solar cells with open-circuit voltages >1 v.Journal of Materials Chemistry A,6(20),9368-9372. |
MLA | Duan, Tainan,et al."F-Substituted oligothiophenes serve as nonfullerene acceptors in polymer solar cells with open-circuit voltages >1 v".Journal of Materials Chemistry A 6.20(2018):9368-9372. |
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