Synthesis of chiral seven-membered cyclic sulfonamides through palladium-catalyzed arylation of cyclic imines

doi:10.1039/c8qo01323c

	Synthesis of chiral seven-membered cyclic sulfonamides through palladium-catalyzed arylation of cyclic imines
	Zhao, Zi-Biao 1,2; Shi, Lei 1; Meng, Fan-Jie 1; Li, Yaming 1; Zhou, Yong-Gui 1,2
刊名	ORGANIC CHEMISTRY FRONTIERS
	2019-05-21
卷号	6 期号:10 页码:1572-1576
ISSN号	2052-4129
DOI	10.1039/c8qo01323c
通讯作者	Shi, Lei(shileichem@dlut.edu.cn) ; Zhou, Yong-Gui(ygzhou@dicp.ac.cn)
英文摘要	An enantioselective palladium-catalyzed addition of arylboronic acids to seven-membered cyclic N-sulfonyl aldimines and ketimines has been developed, giving the chiral cyclic sulfonamides with excellent yields and up to 99% ee.
资助项目	National Natural Science Foundation of China[21772195] ; National Natural Science Foundation of China[21532006] ; Dalian Bureau of Science and Technology[2016RD07] ; Chinese Academy of Sciences[XDB17020300] ; Chinese Academy of Sciences[QYZDJ-SSW-SLH035]
WOS关键词	RING-CLOSING METATHESIS ; PD(II)-CATALYZED ASYMMETRIC ADDITION ; HIGHLY ENANTIOSELECTIVE ARYLATION ; SOLID-PHASE SYNTHESIS ; ARYLBORONIC ACIDS ; ARYLGLYCINE DERIVATIVES ; INHIBITORS ; DESIGN ; ACCESS ; HYDRAZONES
WOS研究方向	Chemistry
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000468001500002
资助机构	National Natural Science Foundation of China ; National Natural Science Foundation of China ; Dalian Bureau of Science and Technology ; Dalian Bureau of Science and Technology ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Dalian Bureau of Science and Technology ; Dalian Bureau of Science and Technology ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Dalian Bureau of Science and Technology ; Dalian Bureau of Science and Technology ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Dalian Bureau of Science and Technology ; Dalian Bureau of Science and Technology ; Chinese Academy of Sciences ; Chinese Academy of Sciences
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/171861]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Shi, Lei; Zhou, Yong-Gui
作者单位	1.Dalian Univ Technol, Sch Chem, State Key Lab Fine Chem, 2 Linggong Rd, Dalian 116024, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Zhao, Zi-Biao,Shi, Lei,Meng, Fan-Jie,et al. Synthesis of chiral seven-membered cyclic sulfonamides through palladium-catalyzed arylation of cyclic imines[J]. ORGANIC CHEMISTRY FRONTIERS,2019,6(10):1572-1576.
APA	Zhao, Zi-Biao,Shi, Lei,Meng, Fan-Jie,Li, Yaming,&Zhou, Yong-Gui.(2019).Synthesis of chiral seven-membered cyclic sulfonamides through palladium-catalyzed arylation of cyclic imines.ORGANIC CHEMISTRY FRONTIERS,6(10),1572-1576.
MLA	Zhao, Zi-Biao,et al."Synthesis of chiral seven-membered cyclic sulfonamides through palladium-catalyzed arylation of cyclic imines".ORGANIC CHEMISTRY FRONTIERS 6.10(2019):1572-1576.