Layered Electron Acceptors by Dimerization of Acenes End- Capped with 1,2,5-Thiadiazoles
Xia, Debin2; Guo, Xin2,3; Chen, Long1,2; Baumgarten, Martin2; Keerthi, Ashok2; Muellen, Klaus2
刊名ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
2016-01-18
卷号55期号:3页码:941-944
关键词Acenes Cyclization Dimerization Excimers Organic Semiconductors
ISSN号1433-7851
DOI10.1002/anie.201508361
文献子类Article
英文摘要Layered electron acceptors D1-4 equipped with terminal 1,2,5-thiadiazole groups have been constructed using a one-pot protocol of acene dimerization. Their molecular structures are determined using single-crystal X-ray diffraction analysis. Photophysical and electrochemical properties of these molecules present a marked dependence on conjugation length and molecular geometry. An aggregation-induced emission peak and an intramolecular excimer emission (IEE) band were observed for D2 and D4, respectively. This work paves the way for the efficient synthesis of layered heteroacenes.
WOS关键词ORGANIC SEMICONDUCTORS ; SOLAR-CELLS ; INTRAMOLECULAR EXCIMER ; CONJUGATED POLYMER ; STATE ; PHOTODIMERIZATION ; FLUORESCENCE ; TRANSISTORS ; DEPENDENCE ; PENTACENE
WOS研究方向Chemistry
语种英语
出版者WILEY-V C H VERLAG GMBH
WOS记录号WOS:000368070000013
内容类型期刊论文
源URL[http://cas-ir.dicp.ac.cn/handle/321008/171482]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者Baumgarten, Martin
作者单位1.Tianjin Univ, Sch Sci, Dept Chem, Tianjin 300072, Peoples R China
2.Max Planck Inst Polymer Res, D-55128 Mainz, Germany
3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
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GB/T 7714
Xia, Debin,Guo, Xin,Chen, Long,et al. Layered Electron Acceptors by Dimerization of Acenes End- Capped with 1,2,5-Thiadiazoles[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2016,55(3):941-944.
APA Xia, Debin,Guo, Xin,Chen, Long,Baumgarten, Martin,Keerthi, Ashok,&Muellen, Klaus.(2016).Layered Electron Acceptors by Dimerization of Acenes End- Capped with 1,2,5-Thiadiazoles.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,55(3),941-944.
MLA Xia, Debin,et al."Layered Electron Acceptors by Dimerization of Acenes End- Capped with 1,2,5-Thiadiazoles".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 55.3(2016):941-944.
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