Ruthenium(III)-Catalyzed beta-Alkylation of Secondary Alcohols with Primary Alcohols

doi:10.1021/acs.organomet.6b00130

	Ruthenium(III)-Catalyzed beta-Alkylation of Secondary Alcohols with Primary Alcohols
	Wang, Qingfu 2; Wu, Kaikai 2; Yu, Zhengkun 1,2
刊名	ORGANOMETALLICS
	2016-05-09
卷号	35 期号:9 页码:1251-1256
ISSN号	0276-7333
DOI	10.1021/acs.organomet.6b00130
文献子类	Article
英文摘要	A Ru(III)-NNN complex bearing a pyridyl-supported pyrazolyl-imidazolyl ligand was synthesized and utilized as the catalyst for the direct beta-alkylation of secondary alcohols with primary alcohols. beta-Alkylated secondary alcohols were obtained in moderate to high yields with water formed as the byproduct through a hydrogen borrowing pathway. The present protocol provides a concise atom-economical and environmentally benign method for C-C bond formation.
WOS关键词	COMPLEX CATALYSTS BEARING ; N-HETEROCYCLIC CARBENE ; PYRAZOLYL-IMIDAZOLYL LIGAND ; ASYMMETRIC TRANSFER HYDROGENATION ; OPPENAUER-TYPE OXIDATION ; RUTHENIUM COMPLEXES ; BORROWING HYDROGEN ; ALPHA-ALKYLATION ; C-ALKYLATION ; NNN LIGAND
WOS研究方向	Chemistry
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000375887300010
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/170934]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Yu, Zhengkun
作者单位	1.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, 354 Fenglin Rd, Shanghai 200032, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Liaoning, Peoples R China
推荐引用方式 GB/T 7714	Wang, Qingfu,Wu, Kaikai,Yu, Zhengkun. Ruthenium(III)-Catalyzed beta-Alkylation of Secondary Alcohols with Primary Alcohols[J]. ORGANOMETALLICS,2016,35(9):1251-1256.
APA	Wang, Qingfu,Wu, Kaikai,&Yu, Zhengkun.(2016).Ruthenium(III)-Catalyzed beta-Alkylation of Secondary Alcohols with Primary Alcohols.ORGANOMETALLICS,35(9),1251-1256.
MLA	Wang, Qingfu,et al."Ruthenium(III)-Catalyzed beta-Alkylation of Secondary Alcohols with Primary Alcohols".ORGANOMETALLICS 35.9(2016):1251-1256.