Aqueous phase hydrogenation of furfural to tetrahydrofurfuryl alcohol on alkaline earth metal modified Ni/Al2O3

doi:10.1039/c6ra05680f

	Aqueous phase hydrogenation of furfural to tetrahydrofurfuryl alcohol on alkaline earth metal modified Ni/Al2O3
	Yang, Yanliang 1,2; Ma, Jiping 1; Jia, Xiuquan 1,3; Du, Zhongtian 1; Duan, Ying 2; Xu, Jie 1
刊名	RSC ADVANCES
	2016
卷号	6 期号:56 页码:51221-51228
ISSN号	2046-2069
DOI	10.1039/c6ra05680f
文献子类	Article
英文摘要	Al2O3 modified by alkaline earth metals M-Al2O3 (M - Mg, Ca, Sr, Ba) was synthesised by coprecipitation method. The nickel-based catalysts supported by M-Al2O3 were prepared by impregnation method. The catalysts were characterized by TEM, N-2 adsorption/desorption, XRD, H-2-TPR, NH3-TPD and XPS, and used for the direct hydrogenation of furfural to tetrahydrofurfuryl alcohol (THFA) in water. The reaction was demonstrated to proceed through furfuryl alcohol as an intermediate. The modification of Al2O3 by alkaline earth metals has a significant effect on the activity and selectivity of THFA. A high yield of THFA was obtained over Ni/Ba-Al2O3 under optimized conditions. Moreover, the catalyst is recyclable and reusable at least four times without significant loss of the conversion of furfural and selectivity of THFA.
WOS关键词	CATALYTIC-HYDROGENATION ; ALLOY CATALYST ; CONVERSION ; BIOMASS ; CHEMICALS ; TRANSFORMATION ; HYDROGENOLYSIS ; CYCLOPENTANONE ; REDUCTION ; PLATFORM
WOS研究方向	Chemistry
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000377515200093
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/170628]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Xu, Jie
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Luoyang Normal Univ, Coll Chem & Chem Engn, Luoyang 471022, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Yang, Yanliang,Ma, Jiping,Jia, Xiuquan,et al. Aqueous phase hydrogenation of furfural to tetrahydrofurfuryl alcohol on alkaline earth metal modified Ni/Al2O3[J]. RSC ADVANCES,2016,6(56):51221-51228.
APA	Yang, Yanliang,Ma, Jiping,Jia, Xiuquan,Du, Zhongtian,Duan, Ying,&Xu, Jie.(2016).Aqueous phase hydrogenation of furfural to tetrahydrofurfuryl alcohol on alkaline earth metal modified Ni/Al2O3.RSC ADVANCES,6(56),51221-51228.
MLA	Yang, Yanliang,et al."Aqueous phase hydrogenation of furfural to tetrahydrofurfuryl alcohol on alkaline earth metal modified Ni/Al2O3".RSC ADVANCES 6.56(2016):51221-51228.