Fe-2(CO)(9)-mediated [5+1] cycloaddition of vinylcyclopropanes and CO for the synthesis of alpha, beta-cyclohexenones

doi:10.1016/j.tet.2016.01.046

	Fe-2(CO)(9)-mediated [5+1] cycloaddition of vinylcyclopropanes and CO for the synthesis of alpha, beta-cyclohexenones
	Liu, Cheng-Hang; Zhuang, Zhe; Bose, Sritama; Yu, Zhi-Xiang
刊名	TETRAHEDRON
	2016-06-02
卷号	72 期号:22 页码:2752-2755
关键词	Fe-2(Co)(9) 5+1 Cycloaddition Vinylcyclopropane Co
ISSN号	0040-4020
DOI	10.1016/j.tet.2016.01.046
文献子类	Article
英文摘要	A Fe-2(CO)(9)-mediated [5+1] cycloaddition of vinylcyclopropanes (VCPs) and CO to alpha, beta-cyclohexenones has been developed. The reaction can tolerate aryl and aliphatic groups at the alpha-position of VCPs, while VCP substrates with vinyl or alkynyl substitutions are not suitable ones. In addition, this reaction can also be used to synthesize bicyclic rings if an aryl group is attached to the vinyl moiety of the substrate. Compared to the Fe(CO)(5)-mediated [5+1] reaction, the use of cheap and safe Fe-2(CO)(9) and abandoning the photo-irradiation conditions are the two major advantages of the present method. (C) 2016 Elsevier Ltd. All rights reserved.
WOS关键词	IRON CARBONYL-COMPLEXES ; DIELS-ALDER REACTION ; TRANSITION-METAL ; ORGANIC-SYNTHESIS ; ALKENYL CYCLOPROPANES ; DIIRON NONACARBONYL ; BOND ACTIVATION ; MONOXIDE ; PENTACARBONYL ; CATALYSIS
WOS研究方向	Chemistry
语种	英语
出版者	PERGAMON-ELSEVIER SCIENCE LTD
WOS记录号	WOS:000376703700008
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/170588]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Yu, Zhi-Xiang
作者单位	Peking Univ, Coll Chem, Key Lab Bioorgan Chem & Mol Engn, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China
推荐引用方式 GB/T 7714	Liu, Cheng-Hang,Zhuang, Zhe,Bose, Sritama,et al. Fe-2(CO)(9)-mediated [5+1] cycloaddition of vinylcyclopropanes and CO for the synthesis of alpha, beta-cyclohexenones[J]. TETRAHEDRON,2016,72(22):2752-2755.
APA	Liu, Cheng-Hang,Zhuang, Zhe,Bose, Sritama,&Yu, Zhi-Xiang.(2016).Fe-2(CO)(9)-mediated [5+1] cycloaddition of vinylcyclopropanes and CO for the synthesis of alpha, beta-cyclohexenones.TETRAHEDRON,72(22),2752-2755.
MLA	Liu, Cheng-Hang,et al."Fe-2(CO)(9)-mediated [5+1] cycloaddition of vinylcyclopropanes and CO for the synthesis of alpha, beta-cyclohexenones".TETRAHEDRON 72.22(2016):2752-2755.