Synthesis of Ni/mesoporous ZSM-5 for direct catalytic conversion of cellulose to hexitols: modulating the pore structure and acidic sites via a nanocrystalline cellulose template

doi:10.1039/c5gc03077c

	Synthesis of Ni/mesoporous ZSM-5 for direct catalytic conversion of cellulose to hexitols: modulating the pore structure and acidic sites via a nanocrystalline cellulose template
	Zhang, Bin 1,3,4; Li, Xiaoru 1,3,4; Wu, Qifan 1,3,4; Zhang, Chao 1,3; Yu, Yancun 1,3,4; Lan, Mingli 1,3; Wei, Xing 4; Ying, Zhong 1,3,4; Liu, Tong 1,3,4; Liang, Guanfeng 2
刊名	GREEN CHEMISTRY
	2016-06-07
卷号	18 期号:11 页码:3315-3323
ISSN号	1463-9262
DOI	10.1039/c5gc03077c
文献子类	Article
英文摘要	Efficient utilization of cellulose is of scientific significance and a great challenge for both fundamental and industrial studies. Herein, we synthesized MesoZSM-5 zeolites by using nanocrystalline cellulose as a template for the first time, and reported the exciting performance of the corresponding non-noble metal catalysts (Ni/MesoZSM-5) for efficient conversion of cellulose to hexitols. By modulating the ratio of the template to precursor, MesoZSM-5 supports were produced with tunable pore structure and acidic sites. With the cooperation of active Ni sites and acidic sites of MesoZSM-5, hexitols were obtained with a high yield of around 60% in the direct conversion of commercial microcrystalline cellulose (MCC). The corresponding correlation between the structural characteristics and catalytic performance was established. This work provides a new approach for efficient utilization of cellulose, as well as gives rise to a sustainable templating method for the synthesis of mesoporous zeolites.
WOS关键词	HYDROLYTIC HYDROGENATION ; LIGNOCELLULOSIC BIOMASS ; BIMETALLIC CATALYSTS ; SELECTIVE CONVERSION ; HIGH-YIELD ; SORBITOL ; ZEOLITE ; GLUCOSE ; SURFACE ; WATER
WOS研究方向	Chemistry
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000378178200016
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/170534]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Zhang, Chao; Zhao, Fengyu
作者单位	1.Chinese Acad Sci, Changchun Inst Appl Chem, Lab Green Chem & Proc, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 3.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, Changchun 130022, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Bin,Li, Xiaoru,Wu, Qifan,et al. Synthesis of Ni/mesoporous ZSM-5 for direct catalytic conversion of cellulose to hexitols: modulating the pore structure and acidic sites via a nanocrystalline cellulose template[J]. GREEN CHEMISTRY,2016,18(11):3315-3323.
APA	Zhang, Bin.,Li, Xiaoru.,Wu, Qifan.,Zhang, Chao.,Yu, Yancun.,...&Zhao, Fengyu.(2016).Synthesis of Ni/mesoporous ZSM-5 for direct catalytic conversion of cellulose to hexitols: modulating the pore structure and acidic sites via a nanocrystalline cellulose template.GREEN CHEMISTRY,18(11),3315-3323.
MLA	Zhang, Bin,et al."Synthesis of Ni/mesoporous ZSM-5 for direct catalytic conversion of cellulose to hexitols: modulating the pore structure and acidic sites via a nanocrystalline cellulose template".GREEN CHEMISTRY 18.11(2016):3315-3323.