Methyllithium-Doped Naphthyl-Containing Conjugated Microporous Polymer with Enhanced Hydrogen Storage Performance

doi:10.1002/chem.201504666

	Methyllithium-Doped Naphthyl-Containing Conjugated Microporous Polymer with Enhanced Hydrogen Storage Performance
	Sun, Lei 2; Xu, Dan 2,3; Li, Gang 1; Shang, Jin 4; Yang, Rui-Xia 2; Deng, Wei-Qiao 2
刊名	CHEMISTRY-A EUROPEAN JOURNAL
	2016-06-01
卷号	22 期号:23 页码:7944-7949
关键词	Doping Hydrogen Microporous Materials Polymers Quantum Chemistry
ISSN号	0947-6539
DOI	10.1002/chem.201504666
文献子类	Article
英文摘要	Hydrogen storage is a primary challenge for using hydrogen as a fuel. With ideal hydrogen storage kinetics, the weak binding strength of hydrogen to sorbents is the key barrier to obtain decent hydrogen storage performance. Here, we reported the rational synthesis of a methyllithium-doped naphthyl-containing conjugated microporous polymer with exceptional binding strength of hydrogen to the polymer guided by theoretical simulations. Meanwhile, the experimental results showed that isosteric heat can reach up to 8.4 kJ mol(-1) and the methyllithium-doped naphthyl-containing conjugated microporous polymer exhibited an enhanced hydrogen storage performance with 150% enhancement compared with its counterpart naphthyl-containing conjugated microporous polymer. These results indicate that this strategy provides a direction for design and synthesis of new materials that meet the US Department of Energy (DOE) hydrogen storage target.
WOS关键词	METAL-ORGANIC FRAMEWORKS ; POROUS AROMATIC FRAMEWORKS ; CARBON-BASED MATERIALS ; HIGH-SURFACE-AREA ; GAS-STORAGE ; UPTAKE CAPACITIES ; LITHIUM IONS ; ADSORPTION ; ALKALI ; LI
WOS研究方向	Chemistry
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000380267100037
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/170344]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Deng, Wei-Qiao
作者单位	1.Univ Western Australia, Sch Mech & Chem Engn, 35 Stirling Highway, Crawley, WA 6009, Australia 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China 3.Soochow Univ, Coll Chem Chem Engn & Mat Sci, Dept Polymer Sci & Engn, Jiangsu Key Lab Adv Funct Polymer Design & Applic, Suzhou 215123, Peoples R China 4.Univ Melbourne, Dept Chem & Biomol Engn, Melbourne, Vic 3010, Australia
推荐引用方式 GB/T 7714	Sun, Lei,Xu, Dan,Li, Gang,et al. Methyllithium-Doped Naphthyl-Containing Conjugated Microporous Polymer with Enhanced Hydrogen Storage Performance[J]. CHEMISTRY-A EUROPEAN JOURNAL,2016,22(23):7944-7949.
APA	Sun, Lei,Xu, Dan,Li, Gang,Shang, Jin,Yang, Rui-Xia,&Deng, Wei-Qiao.(2016).Methyllithium-Doped Naphthyl-Containing Conjugated Microporous Polymer with Enhanced Hydrogen Storage Performance.CHEMISTRY-A EUROPEAN JOURNAL,22(23),7944-7949.
MLA	Sun, Lei,et al."Methyllithium-Doped Naphthyl-Containing Conjugated Microporous Polymer with Enhanced Hydrogen Storage Performance".CHEMISTRY-A EUROPEAN JOURNAL 22.23(2016):7944-7949.