Highly efficient iron phthalocyanine based porous carbon electrocatalysts for the oxygen reduction reaction

doi:10.1039/c6ra13106a

	Highly efficient iron phthalocyanine based porous carbon electrocatalysts for the oxygen reduction reaction
	Huang, Jiahui 3; Jiang, Yu 2,3; Xie, Yan 3; Jin, Xinxin 3; Hu, Qi 3; Chen, Li 1; Xu, Ling 2
刊名	RSC ADVANCES
	2016
卷号	6 期号:82 页码:78737-78742
ISSN号	2046-2069
DOI	10.1039/c6ra13106a
文献子类	Article
英文摘要	Porous carbon (PC) materials with a large surface area and uniform pore sizes have been used as novel electrocatalysts to catalyze the oxygen reduction reaction (ORR). In this work, iron phthalocyanine (FePc) and magnesium oxide (MgO) were used as the precursors and hard-template, respectively, to fabricate FePc-based porous carbon non-noble metal electrocatalysts (NNMEs). The prepared FePc-based porous carbon electrocatalysts possess a high surface area of 555 m(2) g(-1) and a dual mesoporous structure with mean pore sizes of 3.6 nm and 32 nm, and display comparable ORR activity but superior durability than a commercial Pt/C electrocatalyst in alkaline solution. The excellent catalytic performance of FePc-based porous carbon electrocatalysts may be attributed to the large surface area, high density of iron based nano-particles (NPs) encapsulated in carbon layers and high content of doped nitrogen species.
WOS关键词	NITROGEN-DOPED CARBON ; REDUCED GRAPHENE OXIDE ; ELECTROLYTE FUEL-CELLS ; NONPRECIOUS CATALYST ; MESOPOROUS CARBON ; CATHODE CATALYST ; NANOPARTICLES ; ARCHITECTURES ; PERFORMANCE ; ELECTROREDUCTION
WOS研究方向	Chemistry
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000382539300059
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/170210]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Huang, Jiahui; Xu, Ling
作者单位	1.East China Normal Univ, Dept Chem, Shanghai Key Lab Green Chem & Chem Proc, North Zhongshan Rd 3663, Shanghai 200062, Peoples R China 2.Inner Mongolia Univ Nationalities, Coll Chem & Chem Engn, Xilamulun St 996, Tongliao 028000, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, Gold Catalysis Res Ctr, State Key Lab Catalysis, 457 Zhongshan Rd, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Huang, Jiahui,Jiang, Yu,Xie, Yan,et al. Highly efficient iron phthalocyanine based porous carbon electrocatalysts for the oxygen reduction reaction[J]. RSC ADVANCES,2016,6(82):78737-78742.
APA	Huang, Jiahui.,Jiang, Yu.,Xie, Yan.,Jin, Xinxin.,Hu, Qi.,...&Xu, Ling.(2016).Highly efficient iron phthalocyanine based porous carbon electrocatalysts for the oxygen reduction reaction.RSC ADVANCES,6(82),78737-78742.
MLA	Huang, Jiahui,et al."Highly efficient iron phthalocyanine based porous carbon electrocatalysts for the oxygen reduction reaction".RSC ADVANCES 6.82(2016):78737-78742.