A High-Performance Base-Metal Approach for the Oxidative Esterification of 5-Hydroxymethylfurfural

doi:10.1002/cctc.201600484

	A High-Performance Base-Metal Approach for the Oxidative Esterification of 5-Hydroxymethylfurfural
	Xu, Jie 2; Sun, Yuxia 1,2; Ma, Hong 2; Jia, Xiuquan 1,2; Ma, Jiping 2; Luo, Yang 1,2; Gao, Jin 2
刊名	CHEMCATCHEM
	2016-09-21
卷号	8 期号:18 页码:2907-2911
关键词	Biomass Cobalt Hydroxymethylfurfural Manganese Oxidative Esterification Sustainable Chemistry
ISSN号	1867-3880
DOI	10.1002/cctc.201600484
文献子类	Article
英文摘要	Exploring high-performance base-metal approaches for the sustainable production of chemicals from biomass is presently attracting immense interest and is truly important to promote their industrialized application. Herein, CoOx-N/C and alpha-MnO2 were combined as a base-metal catalyst that can achieve high yields of furan-2,5-dimethylcarboxylate (FDMC, 95.6%) for the catalytic oxidative esterification of 5-hydroxymethylfurfural (HMF) without basic additive. The reaction proceeds through fast conversion of HMF to diformylfuran (DFF) with alpha-MnO2 and subsequent transformation of DFF to FDMC by CoOx-N/C. Quantitative X-ray photoelectron spectroscopy (XPS) analysis and density functional theory (DFT) calculations indicated that the pyridinic-N present in doped carbon could behave as a Lewis base to promote the abstraction of hydrogen for the oxidative esterification reaction. Consequently, CoOx-N/C is a high performance catalyst for the synthesis of FDMC from DFF in a neutral medium.
WOS关键词	EFFICIENT AEROBIC OXIDATION ; OXYGEN REDUCTION REACTION ; 2,5-FURANDICARBOXYLIC ACID ; FURAN-2,5-DICARBOXYLIC ACID ; SELECTIVE OXIDATION ; ORGANIC FRAMEWORK ; CARBON NANOTUBES ; OXIDE CATALYSTS ; MILD CONDITIONS ; ALCOHOLS
WOS研究方向	Chemistry
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000386919300009
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/169908]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Xu, Jie; Ma, Hong
作者单位	1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Xu, Jie,Sun, Yuxia,Ma, Hong,et al. A High-Performance Base-Metal Approach for the Oxidative Esterification of 5-Hydroxymethylfurfural[J]. CHEMCATCHEM,2016,8(18):2907-2911.
APA	Xu, Jie.,Sun, Yuxia.,Ma, Hong.,Jia, Xiuquan.,Ma, Jiping.,...&Gao, Jin.(2016).A High-Performance Base-Metal Approach for the Oxidative Esterification of 5-Hydroxymethylfurfural.CHEMCATCHEM,8(18),2907-2911.
MLA	Xu, Jie,et al."A High-Performance Base-Metal Approach for the Oxidative Esterification of 5-Hydroxymethylfurfural".CHEMCATCHEM 8.18(2016):2907-2911.