Studies on Preparation and Properties of Bio-based Polymeric Monomers and Their Bio-based Polymers

doi:10.11777/j.issn1000-3304.2016.16154

	Studies on Preparation and Properties of Bio-based Polymeric Monomers and Their Bio-based Polymers
	Zhao, Zong-bao 2; Chen, Qin 1; Du, Jie-hao 1; Xie, Hai-bo 1; Zheng, Qiang 1
刊名	ACTA POLYMERICA SINICA
	2016-10-20
期号	10 页码:1330-1358
关键词	Catalytic Biorefinery Bio-based Monomers Bio-based Polymers Thermal Properties Mechanical Properties
ISSN号	1000-3304
DOI	10.11777/j.issn1000-3304.2016.16154
文献子类	Review
英文摘要	The search for sustainable resource for polymers production have been obtained much attentions due to the over exploration of fossil resources and environment problems arisen from the use of petroleum based polymeric materials. The modern biorefinery produced a spectrum of biobased chemicals, which can be further upgraded into polymeric monomers for polymer synthesis. This review summarized the latest progress in the synthesis of biobased polymeric monomers from renewable resources such as carbohydrates, lignocellulose and plan oils. According to their structure, those biobased polymeric monomers can be categorised into aliphatic monomers and aromatic monomers including acids, diols, furyl and vanillic monomers. Various strategies, such as catalytic process and fementaion process, were compared in terms of selectivity, yield and feasibility of target biobased monomers. Those biobased monomers can be directly employed as feedstock to prepare biobased polymers, such as polyesters, polyamides, polycarbonates, polyurethanes and polyethers. Besides, both the traditional and novel polymerization processes can be adopted to prepare biobased polymers, such as catalyst free melt condensation, radical polymerization, photocuring process, proton transfer polymerization and enzymatic polycondensations. The influence of various heating methods, catalyst loading, mole ratio, reaction time and temperature to prepare biobased polymers were compared. Those biobased polymers exhibit excellent mechanical and thermal properties and promising properties such as shape memory effect, self-healing properties and bacteria clearing effect, which revealed great potential to replace the petroleum based polymers. Finally, the future development of bio-based polymers has also discussed.
WOS关键词	RENEWABLE RESOURCES ; AEROBIC OXIDATION ; FERULIC ACID ; GAMMA-BUTYROLACTONE ; ITACONIC ACID ; POLY(FERULIC ACID-CO-TYROSINE) ; THERMOSETTING RESINS ; EPSILON-CAPROLACTONE ; POLYESTERS SYNTHESIS ; DELTA-VALEROLACTONE
WOS研究方向	Polymer Science
语种	英语
出版者	SCIENCE PRESS
WOS记录号	WOS:000387628200005
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/169716]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Xie, Hai-bo
作者单位	1.Guizhou Univ, Coll Mat & Met, Dept Polymer Mat & Engn, Guiyang 550025, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Zhao, Zong-bao,Chen, Qin,Du, Jie-hao,et al. Studies on Preparation and Properties of Bio-based Polymeric Monomers and Their Bio-based Polymers[J]. ACTA POLYMERICA SINICA,2016(10):1330-1358.
APA	Zhao, Zong-bao,Chen, Qin,Du, Jie-hao,Xie, Hai-bo,&Zheng, Qiang.(2016).Studies on Preparation and Properties of Bio-based Polymeric Monomers and Their Bio-based Polymers.ACTA POLYMERICA SINICA(10),1330-1358.
MLA	Zhao, Zong-bao,et al."Studies on Preparation and Properties of Bio-based Polymeric Monomers and Their Bio-based Polymers".ACTA POLYMERICA SINICA .10(2016):1330-1358.