Ultrahigh energy storage and ultrafast ion diffusion in borophene-based anodes for rechargeable metal ion batteries

doi:10.1039/c6ta09730h

	Ultrahigh energy storage and ultrafast ion diffusion in borophene-based anodes for rechargeable metal ion batteries
	Liu, Jiehua 4; Rao, Dewei 2; Zhang, Lingyan 3; Meng, Zhaoshun 3; Zhang, Xirui 3; Wang, Yunhui 3; Qiao, Guanjun 2; Shen, Xiangqian 2; Xia, Hui 1; Lu, Ruifeng 1,3
刊名	JOURNAL OF MATERIALS CHEMISTRY A
	2017
卷号	5 期号:5 页码:2328-2338
ISSN号	2050-7488
DOI	10.1039/c6ta09730h
文献子类	Article
英文摘要	Since the turn of the new century, the increasing demand for high-performance energy storage systems has generated considerable interest in rechargeable ion batteries (IBs). However, current IB technologies are not entirely satisfactory, especially the electrodes. We report here, via density functional theory calculations and first principles molecular dynamics simulations, that a borophene anode material has the fascinating properties of ultrahigh energy storage and ultrafast ion diffusion in metal (Li, Na, K, Mg, Al) IBs. Particularly for Li IBs with a borophene anode, a specific density of 3306 mA h g(-1) and a high charging voltage of 1.46 V can be maintained at room temperature. Furthermore, non-ideal borophene anodes, including those with defects or oxidation and nanoribbon samples, still possess good properties for practical applications. This theoretical exploration will provide helpful guidance in searching for available or novel boron nanosheets as promising anode materials to advance commercial IB technology.
WOS关键词	HIGH-CAPACITY ANODE ; LITHIUM STORAGE ; DIRECTIONAL DIFFUSION ; GRAPHENE NANOSHEETS ; CYCLING STABILITY ; RATE CAPABILITY ; LI ; PHOSPHORENE ; NITROGEN ; MOS2
WOS研究方向	Chemistry ; Energy & Fuels ; Materials Science
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000395074300059
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/169572]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Shen, Xiangqian; Xia, Hui; Lu, Ruifeng
作者单位	1.Nanjing Univ Sci & Technol, Sch Mat Sci & Engn, Herbert Gleiter Inst Nanosci, Nanjing 210094, Peoples R China 2.Jiangsu Univ, Sch Mat Sci & Engn, Zhenjiang 212013, Peoples R China 3.Nanjing Univ Sci & Technol, Sch Sci, Atom Mol & Mat Phys Grp, Nanjing 210094, Peoples R China 4.Hefei Univ Technol, Sch Mat Sci & Engn, Future Energy Lab, Hefei 230009, Peoples R China 5.Dalian Inst Chem Phys, Chinese Acad Sci, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Liu, Jiehua,Rao, Dewei,Zhang, Lingyan,et al. Ultrahigh energy storage and ultrafast ion diffusion in borophene-based anodes for rechargeable metal ion batteries[J]. JOURNAL OF MATERIALS CHEMISTRY A,2017,5(5):2328-2338.
APA	Liu, Jiehua.,Rao, Dewei.,Zhang, Lingyan.,Meng, Zhaoshun.,Zhang, Xirui.,...&Lu, Ruifeng.(2017).Ultrahigh energy storage and ultrafast ion diffusion in borophene-based anodes for rechargeable metal ion batteries.JOURNAL OF MATERIALS CHEMISTRY A,5(5),2328-2338.
MLA	Liu, Jiehua,et al."Ultrahigh energy storage and ultrafast ion diffusion in borophene-based anodes for rechargeable metal ion batteries".JOURNAL OF MATERIALS CHEMISTRY A 5.5(2017):2328-2338.