Construction of an operando dual-beam fourier transform infrared spectrometer and its application in the observation of isobutene reactions over nano-sized HZSM-5 zeolite
Xin, Qin3; Liu, Jiaxu1,2; Wang, Jilei1,2; Zhou, Wei1,2; Miao, Cuilan1,2; Xiong, Guang1,2; Guo, Hongchen1,2
刊名CHINESE JOURNAL OF CATALYSIS
2017
卷号38期号:1页码:13-19
关键词Operando Db-ftir Gas-phase Molecular Vibration Spectroscopy Heat Irradiation Influence Real-time Spectrum Real Reaction Condition Heterogeneous Catalysis Aromatization Nano-sized Hzsm-5 Zeolite
ISSN号0253-9837
DOI10.1016/S1872-2067(17)62751-7
文献子类Article
英文摘要An operando dual-beam Fourier transform infrared (DB-FTIR) spectrometer was successfully developed using a facile method. The DB-FTIR spectrometer is suitable for the real-time study of the dynamic surface processes involved in gas/solid heterogeneous catalysis under real reaction conditions because it can simultaneously collect reference and sample spectra. The influence of gas-phase molecular vibration and heat irradiation at real reaction temperatures can therefore be eliminated. The DB-FTIR spectrometer was successfully used to follow the transformation of isobutene over nano-sized HZSM-5 zeolite under real reaction conditions. (C) 2017, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
WOS关键词FT-IR SPECTROSCOPY ; LOW-TEMPERATURE ; CO OXIDATION ; CATALYSTS ; MECHANISM ; METHANE ; ACID ; H-2
WOS研究方向Chemistry ; Engineering
语种英语
出版者SCIENCE PRESS
WOS记录号WOS:000394481400003
内容类型期刊论文
源URL[http://cas-ir.dicp.ac.cn/handle/321008/169562]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者Guo, Hongchen
作者单位1.Dalian Univ Technol, Dept Catalyt Chem & Engn, Dalian 116012, Liaoning, Peoples R China
2.Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116012, Liaoning, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China
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Xin, Qin,Liu, Jiaxu,Wang, Jilei,et al. Construction of an operando dual-beam fourier transform infrared spectrometer and its application in the observation of isobutene reactions over nano-sized HZSM-5 zeolite[J]. CHINESE JOURNAL OF CATALYSIS,2017,38(1):13-19.
APA Xin, Qin.,Liu, Jiaxu.,Wang, Jilei.,Zhou, Wei.,Miao, Cuilan.,...&Guo, Hongchen.(2017).Construction of an operando dual-beam fourier transform infrared spectrometer and its application in the observation of isobutene reactions over nano-sized HZSM-5 zeolite.CHINESE JOURNAL OF CATALYSIS,38(1),13-19.
MLA Xin, Qin,et al."Construction of an operando dual-beam fourier transform infrared spectrometer and its application in the observation of isobutene reactions over nano-sized HZSM-5 zeolite".CHINESE JOURNAL OF CATALYSIS 38.1(2017):13-19.
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