Microporous Crystalline gamma-Al2O3 Replicated from Microporous Covalent Triazine Framework and Its Application as Support for Catalytic Hydrolysis of Ammonia Borane

doi:10.1002/asia.201601631

	Microporous Crystalline gamma-Al2O3 Replicated from Microporous Covalent Triazine Framework and Its Application as Support for Catalytic Hydrolysis of Ammonia Borane
	Chen, Ping 1; Zhang, Miao 1,2; Liu, Lin 1; He, Teng 1; Li, Zhao 1,2; Wu, Guotao 1
刊名	CHEMISTRY-AN ASIAN JOURNAL
	2017-02-16
卷号	12 期号:4 页码:470-475
关键词	Covalent Triazine Framework Hydrolysis Microporous Materials Mesoporous Materials Template Synthesis
ISSN号	1861-4728
DOI	10.1002/asia.201601631
文献子类	Article
英文摘要	Significant progress has been made on the synthesis and application of mesoporous g-alumina. To date, little attention has been paid to the synthesis of microporous crystalline alumina. Here, fabrication of microporous crystalline g-alumina using a microporous covalent triazine framework (CTF-1) as a template is described. Microporous crystalline g-alumina with a micro-meso binary pore system was replicated by infiltration of aluminum nitrate into the micropores of the CTF-1 template through a NH3/water-vapor-induced internal hydrolysis method, followed by thermal treatment, and subsequent removal of the CTF-1 template with a 30% H2O2 aqueous solution. The obtained crystalline g-alumina material exhibits a large surface area (349 m(2)g(-1)) with micropore distribution centered at about 1.27 nm. Ru supported on microporous gamma-Al2O3 can be employed as catalyst for hydrolytic dehydrogenation of ammonia borane, and it exhibits high catalytic activity and good durability. This finding provides a new benchmark for preparing well-defined crystalline microporous alumina materials by a template method, which can be applied in a wide range of fields.
WOS关键词	CHEMICAL HYDROGEN STORAGE ; METAL-ORGANIC FRAMEWORK ; NONIONIC SURFACTANTS ; MESOPOROUS MATERIALS ; ROOM-TEMPERATURE ; FACILE SYNTHESIS ; ALUMINA ; OXIDES ; DEHYDROGENATION ; CAPACITY
WOS研究方向	Chemistry
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000397025000014
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/169408]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Liu, Lin
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Chen, Ping,Zhang, Miao,Liu, Lin,et al. Microporous Crystalline gamma-Al2O3 Replicated from Microporous Covalent Triazine Framework and Its Application as Support for Catalytic Hydrolysis of Ammonia Borane[J]. CHEMISTRY-AN ASIAN JOURNAL,2017,12(4):470-475.
APA	Chen, Ping,Zhang, Miao,Liu, Lin,He, Teng,Li, Zhao,&Wu, Guotao.(2017).Microporous Crystalline gamma-Al2O3 Replicated from Microporous Covalent Triazine Framework and Its Application as Support for Catalytic Hydrolysis of Ammonia Borane.CHEMISTRY-AN ASIAN JOURNAL,12(4),470-475.
MLA	Chen, Ping,et al."Microporous Crystalline gamma-Al2O3 Replicated from Microporous Covalent Triazine Framework and Its Application as Support for Catalytic Hydrolysis of Ammonia Borane".CHEMISTRY-AN ASIAN JOURNAL 12.4(2017):470-475.