Asymmetric Catalytic 1,2-Hydroperoxidation of Isatin-Derived Ketimine with Hydrogen Peroxide in the Crowding Environment of PEGs

doi:10.1021/acs.orglett.7b00032

	Asymmetric Catalytic 1,2-Hydroperoxidation of Isatin-Derived Ketimine with Hydrogen Peroxide in the Crowding Environment of PEGs
	Liu, Yan; Li, Can; Guo, Wengang
刊名	ORGANIC LETTERS
	2017-03-03
卷号	19 期号:5 页码:1044-1047
ISSN号	1523-7060
DOI	10.1021/acs.orglett.7b00032
文献子类	Article
英文摘要	The first enantioselective catalytic 1,2-hydroperoxidation has been achieved in the presence of PEG-600 using an acid base bifunctional chiral squaramide as the organocatalyst, affording a range of enantioenriched alpha-N-substituted hydroperoxides bearing an oxindole moiety with excellent stereoselectivities (up to 99% ee).
WOS关键词	OPTICALLY-ACTIVE HYDROPEROXIDE ; BAEYER-VILLIGER REACTION ; ALPHA,BETA-UNSATURATED KETONES ; ENANTIOSELECTIVE HYDROGENATION ; 3-SUBSTITUTED CYCLOBUTANONES ; RACEMIC HYDROPEROXIDES ; BIFUNCTIONAL CATALYST ; ARTEMISININ QINGHAOSU ; MICHAEL ADDITION ; ALLYLIC ALCOHOLS
WOS研究方向	Chemistry
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000395726100020
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/169364]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Liu, Yan; Li, Can
作者单位	Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Liu, Yan,Li, Can,Guo, Wengang. Asymmetric Catalytic 1,2-Hydroperoxidation of Isatin-Derived Ketimine with Hydrogen Peroxide in the Crowding Environment of PEGs[J]. ORGANIC LETTERS,2017,19(5):1044-1047.
APA	Liu, Yan,Li, Can,&Guo, Wengang.(2017).Asymmetric Catalytic 1,2-Hydroperoxidation of Isatin-Derived Ketimine with Hydrogen Peroxide in the Crowding Environment of PEGs.ORGANIC LETTERS,19(5),1044-1047.
MLA	Liu, Yan,et al."Asymmetric Catalytic 1,2-Hydroperoxidation of Isatin-Derived Ketimine with Hydrogen Peroxide in the Crowding Environment of PEGs".ORGANIC LETTERS 19.5(2017):1044-1047.