Cu-Catalyzed Aerobic Oxidation of Alcohols with a Multi-Functional NMI-TEMPO

doi:10.1002/slct.201800398

	Cu-Catalyzed Aerobic Oxidation of Alcohols with a Multi-Functional NMI-TEMPO
	Li, Guosong 1; Niu, Jingyang 2; Gao, Shuang 1; Wang, Lianyue 1; Bie, Zhixing 2; Shang, Sensen 1
刊名	CHEMISTRYSELECT
	2018-03-29
卷号	3 期号:12 页码:3386-3390
关键词	Aerobic Oxidation Alcohols Copper Multi-functional Tempo
ISSN号	2365-6549
DOI	10.1002/slct.201800398
文献子类	Article
英文摘要	A novel and easily accessible N-methylimidazole derived TEMPO as multi-functional molecule combining with commercially available copper(I) iodide and 4,4'-Di-tert-butyl-2,2'-dipyridyl afford a catalyst system that shows efficient activity for the oxidation of a broad scope of alcohols under air balloon at room temperature. The corresponding aldehydes and ketones were obtained in good to excellent yields. The procedure is readily amenable to scale up. The present catalytic system shows a high chemoselective oxidation of primary alcohols over secondary alcohols. Cu(II) active species generated in situ from Cu(I) is responsible for the oxidation of alcohols.
WOS关键词	SECONDARY BENZYLIC ALCOHOLS ; ROOM-TEMPERATURE ; MOLECULAR-OXYGEN ; CARBONYL-COMPOUNDS ; PROPARGYLIC ALCOHOLS ; MILD CONDITIONS ; ALDEHYDES ; EFFICIENT ; KETONES ; SYSTEM
WOS研究方向	Chemistry
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000429418000004
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/169166]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Gao, Shuang; Wang, Lianyue
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 2.Henan Univ, Inst Mol & Crystal Engn, Henan Key Lab Polyoxometalate Chem, Coll Chem & Chem Engn, Kaifeng 475004, Henan, Peoples R China
推荐引用方式 GB/T 7714	Li, Guosong,Niu, Jingyang,Gao, Shuang,et al. Cu-Catalyzed Aerobic Oxidation of Alcohols with a Multi-Functional NMI-TEMPO[J]. CHEMISTRYSELECT,2018,3(12):3386-3390.
APA	Li, Guosong,Niu, Jingyang,Gao, Shuang,Wang, Lianyue,Bie, Zhixing,&Shang, Sensen.(2018).Cu-Catalyzed Aerobic Oxidation of Alcohols with a Multi-Functional NMI-TEMPO.CHEMISTRYSELECT,3(12),3386-3390.
MLA	Li, Guosong,et al."Cu-Catalyzed Aerobic Oxidation of Alcohols with a Multi-Functional NMI-TEMPO".CHEMISTRYSELECT 3.12(2018):3386-3390.