Sustainable Productions of Organic Acids and Their Derivatives from Biomass via Selective Oxidative Cleavage of C-C Bond

doi:10.1021/acscatal.7b03790

	Sustainable Productions of Organic Acids and Their Derivatives from Biomass via Selective Oxidative Cleavage of C-C Bond
	Wang, Min; Ma, Jiping; Liu, Huifang; Luo, Nengchao; Zhao, Zhitong; Wang, Feng
刊名	ACS CATALYSIS
	2018-03-01
卷号	8 期号:3 页码:2129-2165
关键词	Biomass Lignin 5-hydroxylmethyl Furfural Fatty Acid Oxidation Formic Acid C-c Bond Cleavage
ISSN号	2155-5435
DOI	10.1021/acscatal.7b03790
文献子类	Review
英文摘要	Biomass is renewable and the most abundant carbon resource, and it shows great potential for sustainable production of chemicals in the future. With respect to limited fossil reserves, biomass conversion has aroused global attention. The use of biomass as a resource has developed rapidly in recent years, and various kinds of chemicals could be produced from biomass. Although biomass is annually renewable and abundant, it is important to process it in the most efficient way. Before rushing into biomass conversion, it is necessary to consider what chemicals are reasonably and economically produced from biomass. In this Review, we first analyzed the products from biomass based on the structural properties and economics. Taking into account the oxygen-rich character of the feedstock, it is a reasonable route to convert the biomass into valuable oxygen-containing fine chemicals, among which organic acids are one class of important and widely used fine chemicals. Then, we provided insights into the recent progress in the oxidative cleavage of biomass into organic acids and their derivatives, such as esters and anhydrides. The biomass resources cover the lignocellulose biomass, sugars, chitin, platform molecules, and fats. As biomass resources are generally polymers and the C-C bond is the backbone, the oxidative cleavage of C-C bond can break up the biomass to small molecules and introduce acid functionality at the same time. This Review particularly focuses on the generation of acids via a C-C bond-oxidative-cleavage process. Various methods, catalytic systems, and C-C bond-cleavage mechanisms are summarized. Finally, we conclude with mentioning the challenges in the oxidative conversion of biomass and the possible research direction in this area.
WOS关键词	LIGNIN-MODEL COMPOUNDS ; UNSATURATED FATTY-ACIDS ; CATALYTIC AEROBIC OXIDATION ; RENEWABLE RAW-MATERIALS ; VAPOR-PHASE OXIDATION ; POLYOXOMETALATE POM OXIDATION ; CHARCOAL SUPPORTED PALLADIUM ; 2-STEP HYDROTHERMAL PROCESS ; TRANSITION-METAL CATALYSIS ; BAEYER-VILLIGER OXIDATION
WOS研究方向	Chemistry
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000426804100058
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/168912]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Wang, Feng
作者单位	Chinese Acad Sci, DICP, Dalian Natl Lab Clean Energy DNL, SKLC, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Wang, Min,Ma, Jiping,Liu, Huifang,et al. Sustainable Productions of Organic Acids and Their Derivatives from Biomass via Selective Oxidative Cleavage of C-C Bond[J]. ACS CATALYSIS,2018,8(3):2129-2165.
APA	Wang, Min,Ma, Jiping,Liu, Huifang,Luo, Nengchao,Zhao, Zhitong,&Wang, Feng.(2018).Sustainable Productions of Organic Acids and Their Derivatives from Biomass via Selective Oxidative Cleavage of C-C Bond.ACS CATALYSIS,8(3),2129-2165.
MLA	Wang, Min,et al."Sustainable Productions of Organic Acids and Their Derivatives from Biomass via Selective Oxidative Cleavage of C-C Bond".ACS CATALYSIS 8.3(2018):2129-2165.