Catalytic CO Oxidation by O-2 Mediated by Noble-Metal-Free Cluster Anions Cu2VO3&lt;bold&gt;-&lt;/bold&gt;5-

doi:10.1002/anie.201712129

	Catalytic CO Oxidation by O-2 Mediated by Noble-Metal-Free Cluster Anions Cu2VO3-5-
	Wang, Li-Na 2,3,4; Li, Xiao-Na 2,4; Jiang, Li-Xue 2,3,4; Yang, Bin 1,3,4; Liu, Qing-Yu 2,4; Xu, Hong-Guang 1,4; Zheng, Wei-Jun 1,4; He, Sheng-Gui 2,3,4
刊名	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
	2018-03-19
卷号	57 期号:13 页码:3349-3353
关键词	Carbon Monoxide Copper Heterogeneous Catalysis Mass Spectrometry Vanadium
ISSN号	1433-7851
DOI	10.1002/anie.201712129
文献子类	Article
英文摘要	Catalytic CO oxidation by molecular O-2 is an important model reaction in both the condensed phase and gas-phase studies. Available gas-phase studies indicate that noble metal is indispensable in catalytic CO oxidation by O-2 under thermal collision conditions. Herein, we identified the first example of noble-metal-free heteronuclear oxide cluster catalysts, the copper-vanadium bimetallic oxide clusters Cu2VO3-5- for CO oxidation by O-2. The reactions were characterized by mass spectrometry, photoelectron spectroscopy, and density functional calculations. The dynamic nature of the Cu-Cu unit in terms of the electron storage and release is the driving force to promote CO oxidation and O-2 activation during the catalysis.
WOS关键词	ALUMINUM-OXIDE CLUSTERS ; SINGLE-ATOM CATALYSIS ; GAS-PHASE ; GOLD CLUSTERS ; MOLECULAR-OXYGEN ; CARBON-MONOXIDE ; PLATINUM CLUSTERS ; N2O ; CATIONS ; ACTIVATION
WOS研究方向	Chemistry
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000427235600010
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/168906]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Li, Xiao-Na; Zheng, Wei-Jun; He, Sheng-Gui
作者单位	1.Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Chem, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 4.CAS Res Educ Ctr Excellence Mol Sci, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Wang, Li-Na,Li, Xiao-Na,Jiang, Li-Xue,et al. Catalytic CO Oxidation by O-2 Mediated by Noble-Metal-Free Cluster Anions Cu2VO3-5-[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2018,57(13):3349-3353.
APA	Wang, Li-Na.,Li, Xiao-Na.,Jiang, Li-Xue.,Yang, Bin.,Liu, Qing-Yu.,...&He, Sheng-Gui.(2018).Catalytic CO Oxidation by O-2 Mediated by Noble-Metal-Free Cluster Anions Cu2VO3<bold>-</bold>5-.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,57(13),3349-3353.
MLA	Wang, Li-Na,et al."Catalytic CO Oxidation by O-2 Mediated by Noble-Metal-Free Cluster Anions Cu2VO3<bold>-</bold>5-".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 57.13(2018):3349-3353.