An Amino-Functionalized Metal-Organic Framework, Based on a Rare Ba-12(COO)(18)(NO3)(2) Cluster, for Efficient C-3/C-2/C-1 Separation and Preferential Catalytic Performance

doi:10.1002/chem.201704629

	An Amino-Functionalized Metal-Organic Framework, Based on a Rare Ba-12(COO)(18)(NO3)(2) Cluster, for Efficient C-3/C-2/C-1 Separation and Preferential Catalytic Performance
	Fan, Weidong 2; Wang, Yutong 2; Zhang, Qian 1; Kirchon, Angelo 2; Xiao, Zhenyu 2; Zhang, Liangliang 2; Dai, Fangna 2; Wang, Rongming 2; Sun, Daofeng 2
刊名	CHEMISTRY-A EUROPEAN JOURNAL
	2018-02-09
卷号	24 期号:9 页码:2137-2143
关键词	Gas Storage Ideal Solution Adsorbed Theory (Iast) Light Hydrocarbons Metal-organic Frameworks Selectivity Separation
ISSN号	0947-6539
DOI	10.1002/chem.201704629
文献子类	Article
英文摘要	A barium(II) metal-organic framework (MOF) based on a predesigned amino-functionalized ligand, namely [Ba-2(L)(DMF)(H2O)(NO3)(1/3)]center dot DMF center dot EtOH center dot 2H(2)O (UPC-33) [H3L=4,4'-((2-amino-5-carboxy-1,3-phenylene)bis(ethyne-2,1-diyl))-dibenzoic acid] has been synthesized. UPC-33 is a 3-dimensional 3,18-connected network with fcu topology with a rare twelve-nuclear Ba-12(COO)(18)(NO3)(2) cluster. UPC-33 shows permanent porosity and a high adsorption heat of CO2 (49.92 kJ mol(-1)), which can be used as a platform for selective adsorption of CO2/CH4 (8.09). In addition, UPC-33 exhibits high separation selectivity for C-3 light hydrocarbons with respect to CH4 (228.34, 151.40 for C3H6/CH4, C3H8/CH4 at 273k and 1bar), as shown by single component gas sorption and selectivity calculations. Due to the existence of -NH2 groups in the channels, UPC-33 can effectively catalyze Knoevenagel condensation reactions with high yield, and substrate size and electron dependency.
WOS关键词	HIGHLY SELECTIVE SEPARATION ; LIGHT-HYDROCARBONS ; CARBON-DIOXIDE ; COORDINATION SITES ; CATION-EXCHANGE ; CO2 UPTAKE ; ADSORPTION ; METHANE ; STORAGE ; PORES
WOS研究方向	Chemistry
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000424792600016
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/168834]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Zhang, Liangliang; Sun, Daofeng
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, 457 Zhongshan Rd, Dalian 116023, Peoples R China 2.China Univ Petr East China, Coll Sci, State Key Lab Heavy Oil Proc, 66 Changjiang Rd West, Qingdao 266580, Peoples R China
推荐引用方式 GB/T 7714	Fan, Weidong,Wang, Yutong,Zhang, Qian,et al. An Amino-Functionalized Metal-Organic Framework, Based on a Rare Ba-12(COO)(18)(NO3)(2) Cluster, for Efficient C-3/C-2/C-1 Separation and Preferential Catalytic Performance[J]. CHEMISTRY-A EUROPEAN JOURNAL,2018,24(9):2137-2143.
APA	Fan, Weidong.,Wang, Yutong.,Zhang, Qian.,Kirchon, Angelo.,Xiao, Zhenyu.,...&Sun, Daofeng.(2018).An Amino-Functionalized Metal-Organic Framework, Based on a Rare Ba-12(COO)(18)(NO3)(2) Cluster, for Efficient C-3/C-2/C-1 Separation and Preferential Catalytic Performance.CHEMISTRY-A EUROPEAN JOURNAL,24(9),2137-2143.
MLA	Fan, Weidong,et al."An Amino-Functionalized Metal-Organic Framework, Based on a Rare Ba-12(COO)(18)(NO3)(2) Cluster, for Efficient C-3/C-2/C-1 Separation and Preferential Catalytic Performance".CHEMISTRY-A EUROPEAN JOURNAL 24.9(2018):2137-2143.