Versatile design and synthesis of mesoporous sulfonic acid catalysts

doi:10.1016/j.scib.2018.01.017

	Versatile design and synthesis of mesoporous sulfonic acid catalysts
	Wang, Peng 2,3; Zhao, Yupei 2,3; Liu, Jian 1,4
刊名	SCIENCE BULLETIN
	2018-02-28
卷号	63 期号:4 页码:252-266
关键词	Mesoporous Materials Sulfonic Acid Catalysts Nanoreactors Microenvironment Biomass Conversion
ISSN号	2095-9273
DOI	10.1016/j.scib.2018.01.017
文献子类	Review
英文摘要	Mesoporous sulfonic acid catalysts (MSAC) are widely used in acid-catalyzed reactions, including bio-mass conversions with plenty of polar solvents and precursors. The catalytic efficiency of MSAC is greatly affected by the microenvironment around the sulfonic acid sites. In this review, the progress on modification of microenvironment of MSAC is reviewed over the past decade. Hydrophobic modification allows MSAC prevent the adhesion of water molecules onto sulfonic acid sites, to abate the risk of reduced acid strength and catalytic efficiency. In comparison, hydrophilic properties can bring positive effect on acid-catalyzed reactions with the aid of hydrophilic interaction between polar functional groups on MSAC and hydrophilic groups of specific substrates. Amphiphilic MSAC with tunable wettability for specific substrates and solvents tend to improve the efficiency in certain reactions with mixed solvents or reactants of different polarity, especially for biphasic systems of immiscible liquids. Furthermore, much attention has been attracted on modification of surface to simulate the microenvironment of homogeneous solvents and enzyme biocatalysts in recent research. New trends of this field are also highlighted. (C) 2018 Science China Press. Published by Elsevier B.V. and Science China Press. All rights reserved.
WOS关键词	HIGHLY SELECTIVE CATALYST ; CELLULOSE-DERIVED CARBON ; METAL-ORGANIC FRAMEWORKS ; SOLID ACID ; HETEROGENEOUS CATALYSTS ; LEVULINIC ACID ; IONIC LIQUIDS ; GREEN CHEMISTRY ; GRAPHENE OXIDE ; BIODIESEL SYNTHESIS
WOS研究方向	Science & Technology - Other Topics
语种	英语
出版者	SCIENCE PRESS
WOS记录号	WOS:000425946900010
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/168818]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Wang, Peng; Liu, Jian
作者单位	1.Univ Surrey, Dept Chem & Proc Engn, Guildford GU2 7XH, Surrey, England 2.Changzhou Univ, Sch Petrochem Engn, Jiangsu Key Lab Adv Catalyt Mat & Technol, Changzhou 213164, Peoples R China 3.Changzhou Univ, Adv Catalysis & Green Mfg Collaborat Innovat Ctr, Changzhou 213164, Peoples R China 4.Chinese Acad Sci, Dalian Inst Chem Phys, iChEM, State Key Lab Catalysis, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Wang, Peng,Zhao, Yupei,Liu, Jian. Versatile design and synthesis of mesoporous sulfonic acid catalysts[J]. SCIENCE BULLETIN,2018,63(4):252-266.
APA	Wang, Peng,Zhao, Yupei,&Liu, Jian.(2018).Versatile design and synthesis of mesoporous sulfonic acid catalysts.SCIENCE BULLETIN,63(4),252-266.
MLA	Wang, Peng,et al."Versatile design and synthesis of mesoporous sulfonic acid catalysts".SCIENCE BULLETIN 63.4(2018):252-266.