A mini review on strategies for heterogenization of rhodium-based hydroformylation catalysts

doi:10.1007/s11705-017-1672-9

	A mini review on strategies for heterogenization of rhodium-based hydroformylation catalysts
	Li, Cunyao 1; Wang, Wenlong 1; Yan, Li 1; Ding, Yunjie 1,2
刊名	FRONTIERS OF CHEMICAL SCIENCE AND ENGINEERING
	2018-03-01
卷号	12 期号:1 页码:113-123
关键词	Hydroformylation Porous Organic Ligand (Pol)-supported Catalysts Heterogeneous Catalysis High Stability Immobilization Catalysts
ISSN号	2095-0179
DOI	10.1007/s11705-017-1672-9
文献子类	Review
英文摘要	Hydroformylation has been widely used in industry to manufacture high value-added aldehydes and alcohols, and is considered as the largest homogenously catalyzed process in industry. However, this process often suffers from complicated operation and the difficulty in catalyst recycling. It is highly desirable to develop a heterogeneous catalyst that enables the catalyst recovery without sacrificing the activity and selectivity. There are two strategies to afford such a catalyst for the hydrofromylation: immobilized catalysts on solid support and porous organic ligand (POL)-supported catalysts. In the latter, high concentration of phosphine ligands in the catalyst framework is favorable for the high dispersion of rhodium species and the formation of Rh-P multiple bonds, which endow the catalysts with high activity and stability respectively. Besides, the high linear regioselectivity could be achieved through the copolymerization of vinyl functionalized bidentate ligand (vinyl biphephos) and monodentate ligand (3vPPh(3)) into the catalyst framework. The newly-emerging POL-supported catalysts have great perspectives in the industrial hydroformylation.
WOS关键词	MODIFIED RH/SIO2 CATALYST ; FIXED-BED HYDROFORMYLATION ; EFFICIENT HETEROGENEOUS CATALYSTS ; HIGHLY SELECTIVE HYDROFORMYLATION ; GAS-PHASE HYDROFORMYLATION ; IN-SITU FORMATION ; ASYMMETRIC HYDROFORMYLATION ; INTERNAL OLEFINS ; TETRAPHOSPHORUS LIGANDS ; ISOMERIZATION-HYDROFORMYLATION
WOS研究方向	Engineering
语种	英语
出版者	SPRINGER
WOS记录号	WOS:000425156500014
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/168718]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Yan, Li; Ding, Yunjie
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Li, Cunyao,Wang, Wenlong,Yan, Li,et al. A mini review on strategies for heterogenization of rhodium-based hydroformylation catalysts[J]. FRONTIERS OF CHEMICAL SCIENCE AND ENGINEERING,2018,12(1):113-123.
APA	Li, Cunyao,Wang, Wenlong,Yan, Li,&Ding, Yunjie.(2018).A mini review on strategies for heterogenization of rhodium-based hydroformylation catalysts.FRONTIERS OF CHEMICAL SCIENCE AND ENGINEERING,12(1),113-123.
MLA	Li, Cunyao,et al."A mini review on strategies for heterogenization of rhodium-based hydroformylation catalysts".FRONTIERS OF CHEMICAL SCIENCE AND ENGINEERING 12.1(2018):113-123.