Tuning the Fischer-Tropsch reaction over CoxMnyLa/AC catalysts toward alcohols: Effects of La promotion

doi:10.1016/j.jcat.2018.02.008

	Tuning the Fischer-Tropsch reaction over CoxMnyLa/AC catalysts toward alcohols: Effects of La promotion
	Ding, Yunjie 2,3; Zhao, Ziang 1,2; Lu, Wei 2; Zhu, Hejun 2; Dong, Wenda 2; Lyu, Yuan 2; Liu, Tao 2; Chen, Xingkun 2; Wang, Yuqing 1,2
刊名	JOURNAL OF CATALYSIS
	2018-05-01
卷号	361 页码:156-167
关键词	Fischer-tropsch Synthesis Mixed Alcohols Cobalt Carbide Mn Promoter La Promoter
ISSN号	0021-9517
DOI	10.1016/j.jcat.2018.02.008
文献子类	Article
英文摘要	Selective synthesis of mixed alcohols from syngas (CO + H-2) via Fischer-Tropsch synthesis (FTS) is an alternative one-step one-pot method. Here we report a series of Co-based catalysts supported by activated carbon (AC) and promoted by Mn and La, namely, CoxMnyLa/AC, over which the selectivity to alcohols is usually similar to 26.8% and up to 31.7% at elevated reaction pressure, accompanied by a large amount of olefin byproducts (similar to 30%) that can be further converted to alcohols via a hydroformylation process. Detailed characterizations are performed for the structural properties of catalysts, including physisorption, chemisorption, microscopy, crystal structure, and surface element compositions. The active site of CoxMnyLa/AC catalysts is the highly dispersed metallic Co on the surface of Co2C nanoparticles (Co@Co2C), similar to that of CoxMn/AC catalysts reported previously, while that of CoyLa/AC catalysts is a combination of metallic Co and Co2C phases (Co-Co2C). The result indicates that Mn promoter plays a determinative role in the formation of active sites over CoxMnyLa/AC catalysts. Nevertheless, the La promoter tends to aggregate on the surface of cobalt nanoparticles in the form of La2O3 to promote the CO insertion step and enhance the H-2 chemisorption, so that it can both facilitate the formation of alcohols and make the FTS product class shift to light components. The result proves that the structure of active sites can be established by adding a strong promoter such as Mn, and a second promoter, such as La, can be used to tune the FTS reaction toward alcohols by further modifying its surface properties. (C) 2018 Elsevier Inc. All rights reserved.
WOS关键词	COBALT CARBIDE ; CO HYDROGENATION ; CO/AC CATALYSTS ; MN PROMOTION ; SYNGAS ; SELECTIVITY ; OLEFINS ; PERFORMANCE ; ACIDITY ; LA2O3
WOS研究方向	Chemistry ; Engineering
语种	英语
出版者	ACADEMIC PRESS INC ELSEVIER SCIENCE
WOS记录号	WOS:000431164500017
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/167228]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Ding, Yunjie; Zhu, Hejun
作者单位	1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Ding, Yunjie,Zhao, Ziang,Lu, Wei,et al. Tuning the Fischer-Tropsch reaction over CoxMnyLa/AC catalysts toward alcohols: Effects of La promotion[J]. JOURNAL OF CATALYSIS,2018,361:156-167.
APA	Ding, Yunjie.,Zhao, Ziang.,Lu, Wei.,Zhu, Hejun.,Dong, Wenda.,...&Wang, Yuqing.(2018).Tuning the Fischer-Tropsch reaction over CoxMnyLa/AC catalysts toward alcohols: Effects of La promotion.JOURNAL OF CATALYSIS,361,156-167.
MLA	Ding, Yunjie,et al."Tuning the Fischer-Tropsch reaction over CoxMnyLa/AC catalysts toward alcohols: Effects of La promotion".JOURNAL OF CATALYSIS 361(2018):156-167.