Synthesis and Structure of a Layered Fluoroaluminophosphate and Its Transformation to a Three-Dimensional Zeotype Framework

doi:10.1021/acs.inorgchem.8b01890

	Synthesis and Structure of a Layered Fluoroaluminophosphate and Its Transformation to a Three-Dimensional Zeotype Framework
	Wan, Wei 3; Zou, Xiaodong 3; Guo, Peng 2,3; Afeworki, Mobae 4; Cao, Guang 5; Yun, Yifeng 1,3; Sun, Junliang 3; Su, Jie 3
刊名	INORGANIC CHEMISTRY
	2018-09-17
卷号	57 期号:18 页码:11753-11760
ISSN号	0020-1669
DOI	10.1021/acs.inorgchem.8b01890
通讯作者	Cao, Guang(guang.cao@exxonmobil.com) ; Zou, Xiaodong(xzou@mmk.su.se)
英文摘要	Two-dimensional zeolitic materials have drawn increasing attention because of their structural diversity, high accessible surface areas, and potential as precursors to form novel three-dimensional (3D) structures. Here we report a new layered fluoroaluminophosphate, denoted as EMM-9 (ExxonMobil Material #9), synthesized in the same synthesis system as that for a previously reported 3D framework structure EMM-8 (framework-type code: SFO) using an F- medium and 4-(dimethylamino)pyridine (DMAP) as the organic structure-directing agent. The structure of EMM-9 was solved from rotation electron diffraction data and refined against synchrotron powder X-ray diffraction data. The fluoroaluminophosphate layer of EMM-9 is composed of sti composite building units. The DMAP cations are located between the layers. pi-pi interactions between the DMAP cations and hydrogen bonding between the DMAP cations and layers were identified. The layered EMM-9 structure is closely related to the 3D framework structure of EMM-8 and can be transformed to EMM-8 by calcination.
资助项目	Swedish Research Council (VR) ; Swedish Governmental Agency for Innovation Systems (VINNOVA) ; Knut & Alice Wallenberg Foundation through Project 3DEM-NATUR
WOS关键词	ROTATION ELECTRON-DIFFRACTION ; ALUMINOPHOSPHATE MOLECULAR-SIEVES ; EMBEDDED ISORETICULAR STRUCTURES ; CRYSTALLINE INORGANIC SOLIDS ; X-RAY-DIFFRACTION ; ORGANIC FRAMEWORK ; 8-RING CHANNELS ; PORE-SIZE ; ZEOLITES ; FAMILY
WOS研究方向	Chemistry
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000445165400052
资助机构	Swedish Research Council (VR) ; Swedish Research Council (VR) ; Swedish Governmental Agency for Innovation Systems (VINNOVA) ; Swedish Governmental Agency for Innovation Systems (VINNOVA) ; Knut & Alice Wallenberg Foundation through Project 3DEM-NATUR ; Knut & Alice Wallenberg Foundation through Project 3DEM-NATUR ; Swedish Research Council (VR) ; Swedish Research Council (VR) ; Swedish Governmental Agency for Innovation Systems (VINNOVA) ; Swedish Governmental Agency for Innovation Systems (VINNOVA) ; Knut & Alice Wallenberg Foundation through Project 3DEM-NATUR ; Knut & Alice Wallenberg Foundation through Project 3DEM-NATUR ; Swedish Research Council (VR) ; Swedish Research Council (VR) ; Swedish Governmental Agency for Innovation Systems (VINNOVA) ; Swedish Governmental Agency for Innovation Systems (VINNOVA) ; Knut & Alice Wallenberg Foundation through Project 3DEM-NATUR ; Knut & Alice Wallenberg Foundation through Project 3DEM-NATUR ; Swedish Research Council (VR) ; Swedish Research Council (VR) ; Swedish Governmental Agency for Innovation Systems (VINNOVA) ; Swedish Governmental Agency for Innovation Systems (VINNOVA) ; Knut & Alice Wallenberg Foundation through Project 3DEM-NATUR ; Knut & Alice Wallenberg Foundation through Project 3DEM-NATUR
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/167002]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Zou, Xiaodong; Cao, Guang
作者单位	1.Synfuels China Technol Co Ltd, Leyuan South St 2,1 Yanqi Econ Dev Zone C, Beijing 101407, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Natl Engn Lab Methanol Olefins, Dalian 116023, Peoples R China 3.Stockholm Univ, Dept Mat & Environm Chem, Berzelii Ctr EXSELENT Porous Mat, SE-10691 Stockholm, Sweden 4.ExxonMobil Res & Engn Co, R&D Support Serv, 1545 Route 22 East, Annandale, NJ 08801 USA 5.ExxonMobil Res & Engn Co, Proc Technol Dept, 1545 Route 22 East, Annandale, NJ 08801 USA
推荐引用方式 GB/T 7714	Wan, Wei,Zou, Xiaodong,Guo, Peng,et al. Synthesis and Structure of a Layered Fluoroaluminophosphate and Its Transformation to a Three-Dimensional Zeotype Framework[J]. INORGANIC CHEMISTRY,2018,57(18):11753-11760.
APA	Wan, Wei.,Zou, Xiaodong.,Guo, Peng.,Afeworki, Mobae.,Cao, Guang.,...&Su, Jie.(2018).Synthesis and Structure of a Layered Fluoroaluminophosphate and Its Transformation to a Three-Dimensional Zeotype Framework.INORGANIC CHEMISTRY,57(18),11753-11760.
MLA	Wan, Wei,et al."Synthesis and Structure of a Layered Fluoroaluminophosphate and Its Transformation to a Three-Dimensional Zeotype Framework".INORGANIC CHEMISTRY 57.18(2018):11753-11760.