A Heterogeneous Metal-Free Catalyst for Hydrogenation: Lewis Acid-Base Pairs Integrated into a Carbon Lattice

doi:10.1002/anie.201803977

	A Heterogeneous Metal-Free Catalyst for Hydrogenation: Lewis Acid-Base Pairs Integrated into a Carbon Lattice
	Zheng, Anmin 1; Su, Dang Sheng 2,3; Ding, Yuxiao 5; Huang, Xing 3; Yi, Xianfeng 1; Qiao, Yunxiang 5; Sun, Xiaoyan 4
刊名	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
	2018-10-15
卷号	57 期号:42 页码:13800-13804
关键词	heterogeneous catalysis hydrogenation Lewis pairs metal-free catalysis nanocarbons
ISSN号	1433-7851
DOI	10.1002/anie.201803977
通讯作者	Qiao, Yunxiang(yunxiang.qiao@cec.mpg.de) ; Su, Dang Sheng(dangsheng@fhi-berlin.mpg.de)
英文摘要	Designing heterogeneous metal-free catalysts for hydrogenation is a long-standing challenge in catalysis. Nanodiamond-based carbon materials were prepared that are surface-doped with electron-rich nitrogen and electron-deficient boron. The two heteroatoms are directly bonded to each other to form unquenched Lewis pairs with infinite pi-electron donation from the surrounding graphitic structure. Remarkably, these Lewis pairs can split H-2 to form H+/H- pairs, which subsequently serve as the active species for hydrogenation of different substrates. This unprecedented finding sheds light on the uptake of H-2 across carbon-based materials and suggests that dual Lewis acidity-basicity on the carbon surface may be used to heterogeneously activate a variety of small molecules.
资助项目	NSFC of China[21473223] ; Talents Innovation Project of Dalian[2016RD04] ; NSFC[21522310] ; NSFC[21473244] ; NSF of Hubei[2018CFA009] ; Key Research Program of Frontier Sciences CAS[QYZDB-SSW-SLH026] ; Max Planck Society
WOS关键词	SOLID-STATE NMR ; PROBE MOLECULE ; IONIC LIQUIDS ; ACTIVATION ; SITES ; TRIMETHYLPHOSPHINE ; NANOTUBES ; PYRROLE ; SURFACE
WOS研究方向	Chemistry
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000446826200012
资助机构	NSFC of China ; NSFC of China ; Talents Innovation Project of Dalian ; Talents Innovation Project of Dalian ; NSFC ; NSFC ; NSF of Hubei ; NSF of Hubei ; Key Research Program of Frontier Sciences CAS ; Key Research Program of Frontier Sciences CAS ; Max Planck Society ; Max Planck Society ; NSFC of China ; NSFC of China ; Talents Innovation Project of Dalian ; Talents Innovation Project of Dalian ; NSFC ; NSFC ; NSF of Hubei ; NSF of Hubei ; Key Research Program of Frontier Sciences CAS ; Key Research Program of Frontier Sciences CAS ; Max Planck Society ; Max Planck Society ; NSFC of China ; NSFC of China ; Talents Innovation Project of Dalian ; Talents Innovation Project of Dalian ; NSFC ; NSFC ; NSF of Hubei ; NSF of Hubei ; Key Research Program of Frontier Sciences CAS ; Key Research Program of Frontier Sciences CAS ; Max Planck Society ; Max Planck Society ; NSFC of China ; NSFC of China ; Talents Innovation Project of Dalian ; Talents Innovation Project of Dalian ; NSFC ; NSFC ; NSF of Hubei ; NSF of Hubei ; Key Research Program of Frontier Sciences CAS ; Key Research Program of Frontier Sciences CAS ; Max Planck Society ; Max Planck Society
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/166864]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Su, Dang Sheng; Qiao, Yunxiang
作者单位	1.Chinese Acad Sci, Wuhan Inst Phys & Math, Wuhan 430071, Hubei, Peoples R China 2.Chinese Acad Sci, Dalian Natl Lab Clean Energy, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 3.Max Planck Gesell, Fritz Haber Inst, D-14195 Berlin, Germany 4.Tech Univ Berlin, Dept Chem, D-10623 Berlin, Germany 5.Max Planck Inst Chem Energiekonvers, Stiftstr 34-36, D-45470 Mulheim, Germany
推荐引用方式 GB/T 7714	Zheng, Anmin,Su, Dang Sheng,Ding, Yuxiao,et al. A Heterogeneous Metal-Free Catalyst for Hydrogenation: Lewis Acid-Base Pairs Integrated into a Carbon Lattice[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2018,57(42):13800-13804.
APA	Zheng, Anmin.,Su, Dang Sheng.,Ding, Yuxiao.,Huang, Xing.,Yi, Xianfeng.,...&Sun, Xiaoyan.(2018).A Heterogeneous Metal-Free Catalyst for Hydrogenation: Lewis Acid-Base Pairs Integrated into a Carbon Lattice.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,57(42),13800-13804.
MLA	Zheng, Anmin,et al."A Heterogeneous Metal-Free Catalyst for Hydrogenation: Lewis Acid-Base Pairs Integrated into a Carbon Lattice".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 57.42(2018):13800-13804.