Rapid synthesis of ferrierite zeolite through microwave assisted organic template free route

doi:10.1016/j.micromeso.2018.12.036

	Rapid synthesis of ferrierite zeolite through microwave assisted organic template free route
	Liu, Xuebin 3; Xu, Longya 1; Wei, Pengfei 1,2; Zhu, Xiangxue 1; Wang, Yanan 1,2; Chu, Weifeng 1,2; Xie, Sujuan 1; Yang, Zhiqiang 3; Li, Xiujie 1
刊名	MICROPOROUS AND MESOPOROUS MATERIALS
	2019-05-01
卷号	279 页码:220-227
关键词	Ferrierite Microwave Zeolite synthesis Crystallization
ISSN号	1387-1811
DOI	10.1016/j.micromeso.2018.12.036
通讯作者	Li, Xiujie(xiujieli@dicp.ac.cn) ; Xu, Longya(lyxu@dicp.ac.cn)
英文摘要	Ferrierite (FER) zeolite has been successfully synthesized within 2-3 h through microwave assisted crystallization without using organic structure directing agent. Crystallization temperature and seed content were found to be two of the key factors. XRD patterns and SEM images of the samples taken at different periods of time revealed that seeds were only partially dissolved during the crystallization process and silicate (alumino) species in the gel grew upon the surface of the partially dissolved seed. A core-shell zeolite growth model was proposed. Compared with original seed zeolite, as-synthesized FER zeolite had more regular morphology and larger particle size. The FER crystal size could be controlled in the range of 0.4-3.0 mu m by adjusting the particle size of the seeds. FER obtained through microwave assisted rapid synthesis showed similar catalytic performance in 1-butene skeletal isomerization with the FER obtained through conventional hydrothermal synthesis.
资助项目	National Natural Science Foundation of China[21773233] ; National Natural Science Foundation of China[21376235] ; Natural Science Foundation of Liaoning Province[201602740] ; BP Energy Innovation Laboratory
WOS关键词	SKELETAL ISOMERIZATION ; HYDROTHERMAL SYNTHESIS ; ORGANOTEMPLATE-FREE ; BETA-ZEOLITE ; FER ZEOLITE ; 1-BUTENE ; SYSTEM
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Materials Science
语种	英语
出版者	ELSEVIER SCIENCE BV
WOS记录号	WOS:000460843500025
资助机构	National Natural Science Foundation of China ; National Natural Science Foundation of China ; Natural Science Foundation of Liaoning Province ; Natural Science Foundation of Liaoning Province ; BP Energy Innovation Laboratory ; BP Energy Innovation Laboratory ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Natural Science Foundation of Liaoning Province ; Natural Science Foundation of Liaoning Province ; BP Energy Innovation Laboratory ; BP Energy Innovation Laboratory ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Natural Science Foundation of Liaoning Province ; Natural Science Foundation of Liaoning Province ; BP Energy Innovation Laboratory ; BP Energy Innovation Laboratory ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Natural Science Foundation of Liaoning Province ; Natural Science Foundation of Liaoning Province ; BP Energy Innovation Laboratory ; BP Energy Innovation Laboratory
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/165888]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Xu, Longya; Li, Xiujie
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, 457 Zhongshan Rd, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.BP China Dalian Off, Energy Innovat Lab, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Liu, Xuebin,Xu, Longya,Wei, Pengfei,et al. Rapid synthesis of ferrierite zeolite through microwave assisted organic template free route[J]. MICROPOROUS AND MESOPOROUS MATERIALS,2019,279:220-227.
APA	Liu, Xuebin.,Xu, Longya.,Wei, Pengfei.,Zhu, Xiangxue.,Wang, Yanan.,...&Li, Xiujie.(2019).Rapid synthesis of ferrierite zeolite through microwave assisted organic template free route.MICROPOROUS AND MESOPOROUS MATERIALS,279,220-227.
MLA	Liu, Xuebin,et al."Rapid synthesis of ferrierite zeolite through microwave assisted organic template free route".MICROPOROUS AND MESOPOROUS MATERIALS 279(2019):220-227.