Access to green primary explosives via constructing coordination polymers based on bis-tetrazole oxide and non-lead metals

doi:10.1039/c8gc03973a

	Access to green primary explosives via constructing coordination polymers based on bis-tetrazole oxide and non-lead metals
	Nie, Fude 2; Zhang, Qi 2; Chen, Dong 2; Jing, Dong 1; Fan, Guijuan 2; He, Liu 2; Li, Hongzhen 2; Wang, Wentao 3
刊名	GREEN CHEMISTRY
	2019-04-21
卷号	21 期号:8 页码:1947-1955
ISSN号	1463-9262
DOI	10.1039/c8gc03973a
通讯作者	Zhang, Qi(jackzhang531@caep.cn) ; Wang, Wentao()
英文摘要	An environmentally friendly method to prepare new-generation green primary explosives with excellent performances has been developed on the basis of a coordination chemistry strategy. In the present work, constructing energetic coordination polymers (ECPs) based on tetrazole oxide 1H, 1' H-[ 5,5'-bitetrazole]1,1'- diol (H2BTO) with non-heavy metal cations Mn(II), Co(II), Ni(II), Cu(II), and Zn(II) led to five novel green primary explosives without metal ion and organic pollution. Systematic research is conducted to prove these green ECPs as a novel class of lead-free primary explosives. For example, a thermal stability experiment shows that their thermal decomposition temperatures are all beyond 200 degrees C, while the thermalresistance experiment demonstrates that compounds 1 and 5 can maintain long-term stability under 100 degrees C. And the results based on sensitivity tests and detonation parameter simulation reveal that all these compounds possess excellent detonation and safety properties, far outperforming classical primary explosives such as lead azide. Moreover, a modified Koenen test has been conducted to characterize the explosion capacity of these ECPs and by this method compounds 1, 2, 3, and 5 were demonstrated with fast deflagration-to-detonation transition ability.
资助项目	National Natural Science Foundation of China[21302176] ; National Natural Science Foundation of China[21672210] ; National Natural Science Foundation of China[11302200] ; Development Foundation of CAEP[2013B0302038]
WOS关键词	HIGH-ENERGY-DENSITY ; ORGANIC FRAMEWORKS ; CRYSTAL PACKING ; DETONATION ; SENSITIVITY ; SAFER ; MOFS
WOS研究方向	Chemistry ; Science & Technology - Other Topics
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000465398000033
资助机构	National Natural Science Foundation of China ; National Natural Science Foundation of China ; Development Foundation of CAEP ; Development Foundation of CAEP ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Development Foundation of CAEP ; Development Foundation of CAEP ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Development Foundation of CAEP ; Development Foundation of CAEP ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Development Foundation of CAEP ; Development Foundation of CAEP
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/165556]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Zhang, Qi; Wang, Wentao
作者单位	1.Sichuan Univ, Coll Chem, Minist Educ, Key Lab Green Chem & Technol, Chengdu 610064, Peoples R China 2.China Acad Engn Phys, Inst Chem Mat, Mianyang 621900, Sichuan, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, 457 Zhongshan Rd, Dalian, Peoples R China
推荐引用方式 GB/T 7714	Nie, Fude,Zhang, Qi,Chen, Dong,et al. Access to green primary explosives via constructing coordination polymers based on bis-tetrazole oxide and non-lead metals[J]. GREEN CHEMISTRY,2019,21(8):1947-1955.
APA	Nie, Fude.,Zhang, Qi.,Chen, Dong.,Jing, Dong.,Fan, Guijuan.,...&Wang, Wentao.(2019).Access to green primary explosives via constructing coordination polymers based on bis-tetrazole oxide and non-lead metals.GREEN CHEMISTRY,21(8),1947-1955.
MLA	Nie, Fude,et al."Access to green primary explosives via constructing coordination polymers based on bis-tetrazole oxide and non-lead metals".GREEN CHEMISTRY 21.8(2019):1947-1955.