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Photoluminescence of doped zns nanoparticles under hydrostatic pressure
Li, GH; Su, FH; Ma, BS; Ding, K; Xu, SJ; Chen, W
刊名Physica status solidi b-basic research
2004-11-01
卷号241期号:14页码:3248-3256
ISSN号0370-1972
DOI10.1002/pssb.200405215
通讯作者Li, gh(ghli@red.semi.ac.cn)
英文摘要The pressure dependence of the photoluminescence from zns : mn2+, zns : cu2+, and zns : eu2+ nanoparticles were investigated under hydrostatic pressure up to 6 gpa at room temperature. both the orange emission from the t-4(1) - (6)a(1) transition of mn2+ ions and the blue emission from the da pair transition in the zns host were observed in the mn-doped samples. the measured pressure coefficients are -34.3(8) mev/gpa for the mn-related emission and -3(3) mev/gpa for the da band, respectively. the emission corresponding to the 4f(6)5d(1) - 4f(7) transition of eu2+ ions and the emission related to the transition from the conduction band of zns to the t(2) level of cu2+ ions were observed in the eu- and cu-doped samples, respectively. the pressure coefficient of the eu-related emission was found to be 24.1(5) mev/gpa, while that of the cu-related emission is 63.2(9) mev/gpa. the size dependence of the pressure coefficients for the mn-related emission was also investigated. the mn emission shifts to lower energies with increasing pressure and the shift rate (the absolute value of the pressure coefficient) is larger in the zns : mn2+ nanoparticles than in bulk. moreover, the absolute pressure coefficient increases with the decrease of the particle size. the pressure coefficients calculated based on the crystal field theory are in agreement with the experimental results. (c) 2004 wiley-vch verlag gmbh & co. kgaa, weinheim.
WOS关键词OPTICAL-PROPERTIES ; MN NANOPARTICLES ; ABSORPTION-EDGE ; LUMINESCENCE ; NANOCRYSTALS ; EU2+ ; FLUORESCENCE ; TEMPERATURE ; DEPENDENCE ; EMISSIONS
WOS研究方向Physics
WOS类目Physics, Condensed Matter
语种英语
出版者WILEY-V C H VERLAG GMBH
WOS记录号WOS:000225422300027
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2429432
专题半导体研究所
通讯作者Li, GH
作者单位1.Chinese Acad Sci, Inst Semicond, Natl Lab Superlattices & Microstruct, Beijing 100083, Peoples R China
2.Univ Hong Kong, Dept Phys, Hong Kong, Hong Kong, Peoples R China
3.Univ Hong Kong, CAS, HKU, Joint Lab New Mat, Hong Kong, Hong Kong, Peoples R China
4.Normadics Inc, Stillwater, OK 74074 USA
推荐引用方式
GB/T 7714
Li, GH,Su, FH,Ma, BS,et al. Photoluminescence of doped zns nanoparticles under hydrostatic pressure[J]. Physica status solidi b-basic research,2004,241(14):3248-3256.
APA Li, GH,Su, FH,Ma, BS,Ding, K,Xu, SJ,&Chen, W.(2004).Photoluminescence of doped zns nanoparticles under hydrostatic pressure.Physica status solidi b-basic research,241(14),3248-3256.
MLA Li, GH,et al."Photoluminescence of doped zns nanoparticles under hydrostatic pressure".Physica status solidi b-basic research 241.14(2004):3248-3256.
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