Strong up-conversion emissions in zno:er3+, zno:er3+-yb3+ nanoparticles and their surface modified counterparts | |
Meng, Xiuqing1,2; Liu, Chaoren2; Wu, Fengmin1; Li, Jingbo1,2 | |
刊名 | Journal of colloid and interface science |
2011-06-15 | |
卷号 | 358期号:2页码:334-337 |
关键词 | Sol-gel Zno:er-yb nanoparticles Up-conversion Core/shell Three-photon processes |
ISSN号 | 0021-9797 |
DOI | 10.1016/j.jcis.2011.03.036 |
通讯作者 | Li, jingbo(jbli@semi.ac.cn) |
英文摘要 | Zno:er3+ and zno:er3+-yb3+ nanoparticles (nps) are fabricated by a sol-gel method, afterwards parts of which are separated and surface modified in mo(no3)(3) solution. analyses on phase and structure based on x-ray diffraction (xrd) and high-resolution transmission electron microscopy (hrtem) techniques indicate that er3+ and yb3+ are incorporated into the zno lattice successfully and after mo treatment, a thin layer of moo3 forms on the nps surface, forming core/shell structures. raman scattering spectra reveal the existence of znmoo4 in the shell part. visible up-conversion (uc) is observed in all the samples, with mo treated and untreated zno:er3+ emitting dominant but relatively weak red light, corresponding to f-4(9/2)-i-4(15/2) transition of er3+. in yb3+-codoping systems, the integral uc intensity is enhanced obviously though red emission still dominates the uc spectra before surface modification. in the mo treated system, zno:er3+-yb3+/moo3, green emission is increased while the red is suppressed in comparison to zno:er3+-yb3+, with the intensity of green to red ratio (grr) changing from 0.25 to 8. a novel phenomenon is discovered that the green emissions in our samples involve three-photon processes. (c) 2011 elsevier inc. all rights reserved. |
WOS关键词 | NANOCRYSTALLINE YTTRIA ; OPTICAL SPECTROSCOPY ; GLASSES ; LUMINESCENCE ; TEMPERATURE ; ER3+ ; YB3+ ; GREEN ; FILMS ; OXIDE |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Physical |
语种 | 英语 |
出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
WOS记录号 | WOS:000290188400004 |
内容类型 | 期刊论文 |
URI标识 | http://www.corc.org.cn/handle/1471x/2428201 |
专题 | 半导体研究所 |
通讯作者 | Li, Jingbo |
作者单位 | 1.Zhejiang Normal Univ, Res Ctr Light Emitting Diodes LED, Jinhua 321004, Peoples R China 2.Chinese Acad Sci, Inst Semicond, State Key Lab Superlattices & Microstruct, Beijing 100083, Peoples R China |
推荐引用方式 GB/T 7714 | Meng, Xiuqing,Liu, Chaoren,Wu, Fengmin,et al. Strong up-conversion emissions in zno:er3+, zno:er3+-yb3+ nanoparticles and their surface modified counterparts[J]. Journal of colloid and interface science,2011,358(2):334-337. |
APA | Meng, Xiuqing,Liu, Chaoren,Wu, Fengmin,&Li, Jingbo.(2011).Strong up-conversion emissions in zno:er3+, zno:er3+-yb3+ nanoparticles and their surface modified counterparts.Journal of colloid and interface science,358(2),334-337. |
MLA | Meng, Xiuqing,et al."Strong up-conversion emissions in zno:er3+, zno:er3+-yb3+ nanoparticles and their surface modified counterparts".Journal of colloid and interface science 358.2(2011):334-337. |
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