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Composition deviation of arrays of fept nanoparticles starting from poly(styrene)-poly(4-vinylpyridine) micelles
Qu, S.; Zhang, X. W.; Gao, Y.; You, J. B.; Fan, Y. M.; Yin, Z. G.; Chen, N. F.
刊名Nanotechnology
2008-04-02
卷号19期号:13页码:7
ISSN号0957-4484
DOI10.1088/0957-4484/19/13/135704
通讯作者Zhang, x. w.(xwzhang@semi.ac.cn)
英文摘要Ordered arrays of fept nanoparticles were prepared using a diblock polymer micellar method combined with plasma treatment. rutherford backscattering spectroscopy analyses reveal that the molar ratios of fe to pt in metal-salt-loaded micelles deviate from those when metal precursors are added, and that the plasma treatment processes have little influence upon the compositions of the resulting fept nanoparticles. the results from fourier transform infrared spectroscopy show that the maximum loadings of fecl(3) and h(2)ptcl(6) inside poly( styrene)-poly(4-vinylpyridine) micelles are different. the composition deviation of fept nanoparticles is attributed to the fact that one fecl3 molecule coordinates with a single 4-vinylpyridine (4vp) unit, while two neighboring and uncomplexed 4vp units are required for one h(2)ptcl(6) molecule. additionally, we demonstrate that the center-to-center distances of the neighboring fept nanoparticles can also be tuned by varying the drawing velocity.
WOS关键词DIBLOCK COPOLYMER MICELLES ; ORDERED ARRAYS ; OXIDE NANOPARTICLES ; BLOCK-COPOLYMERS ; SURFACES ; FILMS ; NANOSTRUCTURES ; TEMPLATES ; SYSTEMS ; POLYSTYRENE-BLOCK-POLY(4-VINYLPYRIDINE)
WOS研究方向Science & Technology - Other Topics ; Materials Science ; Physics
WOS类目Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied
语种英语
出版者IOP PUBLISHING LTD
WOS记录号WOS:000254174400020
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2427353
专题半导体研究所
通讯作者Zhang, X. W.
作者单位Chinese Acad Sci, Inst Semicond, Key Lab Semicond Mat Sci, Beijing 100083, Peoples R China
推荐引用方式
GB/T 7714
Qu, S.,Zhang, X. W.,Gao, Y.,et al. Composition deviation of arrays of fept nanoparticles starting from poly(styrene)-poly(4-vinylpyridine) micelles[J]. Nanotechnology,2008,19(13):7.
APA Qu, S..,Zhang, X. W..,Gao, Y..,You, J. B..,Fan, Y. M..,...&Chen, N. F..(2008).Composition deviation of arrays of fept nanoparticles starting from poly(styrene)-poly(4-vinylpyridine) micelles.Nanotechnology,19(13),7.
MLA Qu, S.,et al."Composition deviation of arrays of fept nanoparticles starting from poly(styrene)-poly(4-vinylpyridine) micelles".Nanotechnology 19.13(2008):7.
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