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Investigation of native defects and property of bulk zno single crystal grown by a closed chemical vapor transport method
Wei, Xuecheng; Zhao, Youwen; Dong, Zhiyuan; Li, Jinmin
刊名Journal of crystal growth
2008-02-01
卷号310期号:3页码:639-645
关键词Defects X-ray diffraction Growth from vapor Oxides Semiconducting ii-vi materials
ISSN号0022-0248
DOI10.1016/j.jcrysgro.2007.10.080
通讯作者Wei, xuecheng(xcwei@semi.ac.cn)
英文摘要Hall effect, raman scattering, photoluminescence spectroscopy (pl), optical absorption (oa), mass spectroscopy, and x-ray diffraction have been used to study bulk zno single crystal grown by a closed chemical vapor transport method. the results indicate that shallow donor impurities (ga and al) are the dominant native defects responsible for n-type conduction of the zno single crystal. pl and oa results suggest that the as-grown and annealed zno samples with poor lattice perfection exhibit strong deep level green photoluminescence and weak ultraviolet luminescence. the deep level defect in as-grown zno is identified to be oxygen vacancy. after high-temperature annealing, the deep level photoluminescence is suppressed in zno crystal with good lattice perfection. in contrast, the photoluminescence is nearly unchanged or even enhanced in zno crystal with grain boundary or mosaic structure. this result indicates that a trapping effect of the defect exists at the grain boundary in zno single crystal. (c) 2007 elsevier b.v. all rights reserved.
WOS关键词HYDROTHERMAL METHOD ; ZINC-OXIDE ; THIN-FILMS ; ACCEPTORS ; DEVICES ; VACANCIES ; PROGRESS ; DONORS
WOS研究方向Crystallography ; Materials Science ; Physics
WOS类目Crystallography ; Materials Science, Multidisciplinary ; Physics, Applied
语种英语
出版者ELSEVIER SCIENCE BV
WOS记录号WOS:000253016900022
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2427293
专题半导体研究所
通讯作者Wei, Xuecheng
作者单位Chinese Acad Sci, Inst Semicond, Beijing 100083, Peoples R China
推荐引用方式
GB/T 7714
Wei, Xuecheng,Zhao, Youwen,Dong, Zhiyuan,et al. Investigation of native defects and property of bulk zno single crystal grown by a closed chemical vapor transport method[J]. Journal of crystal growth,2008,310(3):639-645.
APA Wei, Xuecheng,Zhao, Youwen,Dong, Zhiyuan,&Li, Jinmin.(2008).Investigation of native defects and property of bulk zno single crystal grown by a closed chemical vapor transport method.Journal of crystal growth,310(3),639-645.
MLA Wei, Xuecheng,et al."Investigation of native defects and property of bulk zno single crystal grown by a closed chemical vapor transport method".Journal of crystal growth 310.3(2008):639-645.
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