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	Hydrated alkali metal halides as efficient catalysts for the synthesis of cyclic carbonates from co2 and epoxides
	Zhou Xi1,2; Zhang Yi1,2; Yang Xiangui1; Yao Jie1; Wang Gongying1
刊名	Chinese journal of catalysis
	2010-07-01
卷号	31期号:7页码:765-768
关键词	Carbon dioxide Propylene oxide Propylene carbonate Cyclic carbonate Hydrated alkali metal halide
ISSN号	0253-9837
DOI	10.1016/s1872-2067(09)60086-3
通讯作者	Zhou xi()
英文摘要	The synthesis of propylene carbonate from carbon dioxide and propylene oxide using hydrated alkali metal halides as catalysts in the absence of a co-catalyst and a solvent was investigated. the hydrated alkali metal halides showed much higher catalytic activity than the anhydrous alkali metal halides. sodium iodide dihydrate was found to be the most efficient among them and it gave a 97% yield of propylene carbonate at 120 degrees c under 1 mpa within 1.5 h. the corresponding cyclic carbonates from co2 and other epoxides using sodium iodide dihydrate as catalyst were also successfully synthesized.
WOS关键词	ATMOSPHERIC-PRESSURE ; DIOXIDE ; MG
WOS研究方向	Chemistry ; Engineering
WOS类目	Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
语种	英语
出版者	SCIENCE PRESS
WOS记录号	WOS:000280868900008
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2413629
专题	中国科学院大学
通讯作者	Zhou Xi
作者单位	1.Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Sichuan, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Zhou Xi,Zhang Yi,Yang Xiangui,et al. Hydrated alkali metal halides as efficient catalysts for the synthesis of cyclic carbonates from co2 and epoxides[J]. Chinese journal of catalysis,2010,31(7):765-768.
APA	Zhou Xi,Zhang Yi,Yang Xiangui,Yao Jie,&Wang Gongying.(2010).Hydrated alkali metal halides as efficient catalysts for the synthesis of cyclic carbonates from co2 and epoxides.Chinese journal of catalysis,31(7),765-768.
MLA	Zhou Xi,et al."Hydrated alkali metal halides as efficient catalysts for the synthesis of cyclic carbonates from co2 and epoxides".Chinese journal of catalysis 31.7(2010):765-768.

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