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	A three-dimensional supramolecular complex {[co(h(2)btec)(2,2 '-bipy)(h2o)(3)]center dot h2o}(n) assembled via hydrogen bonding and pi-pi stacking interactions
	Sun Ming-Ling1,2; Yin Pei-Xiu1; Li Zhao-Ji1; Cao Xin-Yi1; Cheng Jian-Kai1; Qin Ye-Yan1; Yao Yuan-Gen1
刊名	Chinese journal of structural chemistry
	2010
卷号	29期号:5页码:726-731
关键词	Cobalt compound 1,2,4,5-benzenetetracarboxylic acid 2,2 '-bipyridine Supramolecular network Crystal structure
ISSN号	0254-5861
通讯作者	Yao yuan-gen(yyg@fjirsm.ac.cn)
英文摘要	A new cobalt compound, {[co(h(2)btec)(2,2'-bipy)(h2o)(3)]center dot h2o}(n) (1, h(4)btec = 1,2,4,5-benzenetetracarboxylic acid, 2,2'-bipy = 2,2'-bipyridine), has been synthesized and characterized by single-crystal x-ray diffraction, elemental analysis, ir and x-ray powder diffraction. the crystal belongs to the triclinic system, space group p (1) over bar, with a = 7.230(3), b = 11.626(5), c = 14.001(6) angstrom, alpha = 108.12(0), beta = 95.85(0)degrees, v = 1095.33(157) angstrom(3), c20h20con2o12, m-r = 539.31, z = 2, d-c = 1.635 g/cm(3), mu = 0.855 mm(-1), f(000) = 554, r = 0.0427 and wr = 0.1042 for 3883 observed reflections (i > 2 sigma(i)). the title compound features a discrete molecular structure, which is connected with each other through extensive o-h center dot center dot center dot o hydrogen bonds into an intricate 3d supramolecular network. additionally, two different patterns of pi-pi stacking interactions further consolidate the framework.
WOS关键词	METAL-COMPLEXES ; CRYSTAL-STRUCTURE ; TRANSITION-METAL ; SOLID-STATE ; COMPOUND ; PATTERNS ; CHELATE ; LIGANDS
WOS研究方向	Chemistry ; Crystallography
WOS类目	Chemistry, Inorganic & Nuclear ; Crystallography
语种	英语
出版者	CHINESE JOURNAL STRUCTURAL CHEMISTRY
WOS记录号	WOS:000278259900012
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2412908
专题	中国科学院大学
通讯作者	Yao Yuan-Gen
作者单位	1.Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Fujian, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式 GB/T 7714	Sun Ming-Ling,Yin Pei-Xiu,Li Zhao-Ji,et al. A three-dimensional supramolecular complex {[co(h(2)btec)(2,2 '-bipy)(h2o)(3)]center dot h2o}(n) assembled via hydrogen bonding and pi-pi stacking interactions[J]. Chinese journal of structural chemistry,2010,29(5):726-731.
APA	Sun Ming-Ling.,Yin Pei-Xiu.,Li Zhao-Ji.,Cao Xin-Yi.,Cheng Jian-Kai.,...&Yao Yuan-Gen.(2010).A three-dimensional supramolecular complex {[co(h(2)btec)(2,2 '-bipy)(h2o)(3)]center dot h2o}(n) assembled via hydrogen bonding and pi-pi stacking interactions.Chinese journal of structural chemistry,29(5),726-731.
MLA	Sun Ming-Ling,et al."A three-dimensional supramolecular complex {[co(h(2)btec)(2,2 '-bipy)(h2o)(3)]center dot h2o}(n) assembled via hydrogen bonding and pi-pi stacking interactions".Chinese journal of structural chemistry 29.5(2010):726-731.

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