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Synthesis and photocatalytic activity of highly dispersed tio2/sba-15
Zhang Shu-Cui1,2; Jiang Dong1; Tang Tao1,2; Li Jun-Hua1,2; Xu Yao1
刊名Acta physico-chimica sinica
2010-05-01
卷号26期号:5页码:1330-1336
关键词Photocatalysis Carboxylate-modified Tio2 Sba-15 Solvothermal
ISSN号1000-6818
DOI10.3866/pku.whxb20100520
通讯作者Jiang dong(jdred@sxicc.ac.cn)
英文摘要Highly dispersed tio2/sba-15 photocatalysts were successfully synthesized by solvothermal treatment using titanium n-butoxide (tb) and carboxylate. modified sba-15 (cooh/sba-15) as raw materials. the good dispersive carboxyl groups of cooh/sba-15 coordinated with tb molecules to anchor them. after solvothermal treatment, the tb molecules were transformed into tio2 nanoparticles and finally formed the tio2/sba-15 products. the products were calcined to improve the crystallization of tio2 and to remove the organic compounds. as. obtained tio2/sba-15 photocatalysts were characterized by x. ray diffraction (xrd), nitrogen adsorption, fourier transform infrared (fi-ir) spectroscopy, and transmission electron microscopy (tem). analytical results showed that the as. obtained tio2/sba-15 photocatalysts possessed a better mesoporous structure and a larger specific surface area. the highly crystalline anatase tio2 nanocrystals dispersed well on the surface of sba-15. rhodamine b (rhb), as a photodegradation target, was used to evaluate photocatalytic performance under uv light irradiation. the as. obtained tio2/sba-15 photocatalysts exhibited much better photocatalytic activity compared with the photocatalysts prepared by a post. synthesis impregnation method.
WOS关键词SUPPORTED TIO2 PHOTOCATALYSTS ; MESOPOROUS SILICA ; RAMAN-SPECTRUM ; ANATASE TIO2 ; TITANIA ; NANOPARTICLES ; SBA-15 ; DEGRADATION ; ADSORPTION ; FILMS
WOS研究方向Chemistry
WOS类目Chemistry, Physical
语种英语
出版者PEKING UNIV PRESS
WOS记录号WOS:000277881600024
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2409955
专题中国科学院大学
通讯作者Jiang Dong
作者单位1.Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Zhang Shu-Cui,Jiang Dong,Tang Tao,et al. Synthesis and photocatalytic activity of highly dispersed tio2/sba-15[J]. Acta physico-chimica sinica,2010,26(5):1330-1336.
APA Zhang Shu-Cui,Jiang Dong,Tang Tao,Li Jun-Hua,&Xu Yao.(2010).Synthesis and photocatalytic activity of highly dispersed tio2/sba-15.Acta physico-chimica sinica,26(5),1330-1336.
MLA Zhang Shu-Cui,et al."Synthesis and photocatalytic activity of highly dispersed tio2/sba-15".Acta physico-chimica sinica 26.5(2010):1330-1336.
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