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Surfactant-free self-assembly of nanocrystals into ellipsoidal architectures
Peng, Bo1,2; Chen, Dong1; Deng, Zhengtao1,2; Wen, Ting1,2; Meng, Xianwei1; Ren, Xiangling1; Ren, Jun1; Tang, Fangqiong1
刊名Chemphyschem
2010-12-03
卷号11期号:17页码:3744-3751
关键词Biomimetic synthesis Crystal growth Electrostatic interactions Nanostructures Self-assembly
ISSN号1439-4235
DOI10.1002/cphc.201000458
通讯作者Tang, fangqiong(tangfq@mail.ipc.ac.cn)
英文摘要A simple approach to control the self-assembly of zns nanocrystals into well-defined, uniform, three-dimensional, micrometer-scale, solid ellipsoidal structures with rattle-type, multishelled, and hollow architectures is presented. there is no surfactant or small molecule to assist the self-assembly of the nanocrystals. a possible mechanism of the controlled self-assembly is proposed. the growth process can be divided into two stages: 1) the formation of ellipsoidal architectures via oriented aggregation, the growth kinetics of which is primarily attributed to the charge-charge, charge-dipole, and dipole-dipole interactions of preformed zns nanocrystals; and 2) ostwald ripening, which results in multishelled, rattle-type, and hollow structures. this self-assembly concept is also applicable to other metal sulfides.
WOS关键词ORIENTED ATTACHMENT MECHANISM ; CRYSTAL-GROWTH ; OPTICAL-PROPERTIES ; PHOTONIC CRYSTALS ; NANOWIRES ; NANOPARTICLES ; AGGREGATION ; FABRICATION ; NANORODS ; ZNS
WOS研究方向Chemistry ; Physics
WOS类目Chemistry, Physical ; Physics, Atomic, Molecular & Chemical
语种英语
出版者WILEY-V C H VERLAG GMBH
WOS记录号WOS:000285256900025
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2408832
专题中国科学院大学
通讯作者Tang, Fangqiong
作者单位1.Chinese Acad Sci, Lab Controllable Preparat & Applicat Nanomat, Tech Inst Phys & Chem, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Peng, Bo,Chen, Dong,Deng, Zhengtao,et al. Surfactant-free self-assembly of nanocrystals into ellipsoidal architectures[J]. Chemphyschem,2010,11(17):3744-3751.
APA Peng, Bo.,Chen, Dong.,Deng, Zhengtao.,Wen, Ting.,Meng, Xianwei.,...&Tang, Fangqiong.(2010).Surfactant-free self-assembly of nanocrystals into ellipsoidal architectures.Chemphyschem,11(17),3744-3751.
MLA Peng, Bo,et al."Surfactant-free self-assembly of nanocrystals into ellipsoidal architectures".Chemphyschem 11.17(2010):3744-3751.
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