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	Ree and c-o isotopic geochemistry of calcites from the world-class huize pb-zn deposits, yunnan, china: implications for the ore genesis
	Huang Zhilong1,2; Li Xiaobiao1,3; Zhou Meifu2; Li Wenbo1,4; Jin Zhongguo1
刊名	Acta geologica sinica-english edition
	2010
卷号	84期号:3页码:597-613
关键词	Gangue calcite Ree geochemistry C-o isotope Ore-forming fluid Huize pb-zn deposits
ISSN号	1000-9515
通讯作者	Huang zhilong(huangzhilong@vip.gyig.ac.cn)
英文摘要	The world-class huize pb-zn deposits of yunnan province, in southwestern china, located in the center of the sichuan-yunnan-guizhou pb-zn polymetallic metallogenic province, has pb+zn reserves of more than 5 million tons at pb+zn grade of higher than 25% and contains abundant associated metals, such as ag, ge, cd, and ga. the deposits are hosted in the lower carboniferous carbonate strata and the permian emeishan basalts which distributed in the northern and southwestern parts of the orefield. calcite is the only gangue mineral in the primary ores of the deposits and can be classified into three types, namely lumpy, patch and vein calcites in accordance with their occurrence. there is not intercalated contact between calcite and ore minerals and among the three types of calcite, indicating that they are the same ore-forming age with different stages and its forming sequence is from lumpy to patch to vein calcites. this paper presents the rare earth element (ree) and c-o isotopic compositions of calcites in the huize pb-zn deposits. from lumpy to patch to vein calcites, ree contents decrease as lree/hree ratios increase. the chondrite-normalized ree patterns of the three types of calcites are characterized by lree-rich shaped, in which the lumpy calcite shows (la)(n) < (ce)(n) < (pr)(n) approximate to (nd)(n) with eu/eu* < 1, the patch calcite has (la)(n) < (ce)(n) < (pr)(n) approximate to (nd)(n) with eu/eu* > 1, and the vein calcite displays (la)(n) > (ce)(n) > (pr)(n) > (nd)(n) with eu/eu* > 1. the ree geochemistry of the three types of calcite is different from those of the strata of various age and permian emeishan basalt exposed in the orefield. the delta 13c(pdb) and delta 18o(smow) values of the three types of calcites vary from -3.5 parts per thousand to -2.1 parts per thousand and 16.7 parts per thousand to 18.6 parts per thousand, respectively, falling within a small field between primary mantle and marine carbonate in the delta 13c(pdb) vs delta 18o(smow) diagram. various lines of evidence demonstrate that the three types of calcites in the deposits are produced from the same source with different stages. the ore-forming fluids of the deposits resulted from crustal-mantle mixing processes, in which the mantle-derived fluid components might be formed from degassing of mantle or/and magmatism of the permian emeishan basalts, and the crustal fluid was mainly provided by carbonate strata in the orefield. the ore-forming fluids in the deposits were homogenized before mineralization, and the ore-forming environment varied from relatively reducing to oxidizing.
WOS关键词	RARE-EARTH-ELEMENT ; PERMIAN-TRIASSIC BOUNDARY ; EMEISHAN FLOOD BASALTS ; LARGE IGNEOUS PROVINCE ; WESTERN-AUSTRALIA ; SOUTHWEST CHINA ; FORMING FLUIDS ; TRACE-ELEMENT ; ITAPIRAPUA CARBONATITE ; HYDROTHERMAL FLUORITE
WOS研究方向	Geology
WOS类目	Geosciences, Multidisciplinary
语种	英语
出版者	WILEY-BLACKWELL
WOS记录号	WOS:000278516400013
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2408047
专题	中国科学院大学
通讯作者	Huang Zhilong
作者单位	1.Chinese Acad Sci, State Key Lab Ore Deposit Geochem, Inst Geochem, Guiyang 550002, Peoples R China 2.Univ Hong Kong, Dept Earth Sci, Hong Kong, Hong Kong, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China 4.Peking Univ, MOE Key Lab Orogen Belts & Crustal Evolut, Beijing 100871, Peoples R China
推荐引用方式 GB/T 7714	Huang Zhilong,Li Xiaobiao,Zhou Meifu,et al. Ree and c-o isotopic geochemistry of calcites from the world-class huize pb-zn deposits, yunnan, china: implications for the ore genesis[J]. Acta geologica sinica-english edition,2010,84(3):597-613.
APA	Huang Zhilong,Li Xiaobiao,Zhou Meifu,Li Wenbo,&Jin Zhongguo.(2010).Ree and c-o isotopic geochemistry of calcites from the world-class huize pb-zn deposits, yunnan, china: implications for the ore genesis.Acta geologica sinica-english edition,84(3),597-613.
MLA	Huang Zhilong,et al."Ree and c-o isotopic geochemistry of calcites from the world-class huize pb-zn deposits, yunnan, china: implications for the ore genesis".Acta geologica sinica-english edition 84.3(2010):597-613.

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