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	Indene-c-60 bisadduct: a new acceptor for high-performance polymer solar cells
	He, Youjun2,3; Chen, Hsiang-Yu1; Hou, Jianhui1; Li, Yongfang2
刊名	Journal of the american chemical society
	2010-02-03
卷号	132期号:4页码:1377-1382
ISSN号	0002-7863
DOI	10.1021/ja908602j
通讯作者	Hou, jianhui(jianhuih@solarmer.com)
英文摘要	Polymer solar cells (pscs) are commonly composed of a blend film of a conjugated polymer donor and a soluble c-60 derivative acceptor sandwiched between an ito anode and a low-workfunction metal cathode. poly(3-hexylthiophene) (p3ht) and [6,6]-phenyl-c-61-butyric acid methyl ester (pcbm) are the most widely used donor and acceptor materials, respectively. however, the low lumo energy level of pcbm limits the open circuit voltage (v-oc) of the p3ht-based pscs to ca. 0.6 v. here we synthesized a new soluble c-60 derivative, indene-c-60 bisadduct (icba), with a lumo energy level 0. 17 ev higher than that of pcbm. the psc based on p3ht with icba as acceptor shows a higher v-oc of 0.84 v and higher power conversion efficiency (pce) of 5.44% under the illumination of am1.5, 100 mw/cm(2), while the psc based on p3ht/pcbm displays a v-oc of 0.58 v and pce of 3.88% under the same experimental conditions. the results indicate that icba is an alternative high-performance acceptor and could be widely used in high-performance pscs.
WOS关键词	OPEN-CIRCUIT VOLTAGE ; PHOTOVOLTAIC DEVICES ; ORGANIC PHOTOVOLTAICS ; FULLERENE DERIVATIVES ; ELECTRON-ACCEPTORS ; EFFICIENCY ; METHANOFULLERENES ; DESIGN ; POLYTHIOPHENES ; NETWORK
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000275084800054
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2406357
专题	中国科学院大学
通讯作者	Hou, Jianhui
作者单位	1.Solarmer Energy Inc, El Monte, CA 91731 USA 2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Organ Solids, Inst Chem, Beijing 100190, Peoples R China 3.Grad Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	He, Youjun,Chen, Hsiang-Yu,Hou, Jianhui,et al. Indene-c-60 bisadduct: a new acceptor for high-performance polymer solar cells[J]. Journal of the american chemical society,2010,132(4):1377-1382.
APA	He, Youjun,Chen, Hsiang-Yu,Hou, Jianhui,&Li, Yongfang.(2010).Indene-c-60 bisadduct: a new acceptor for high-performance polymer solar cells.Journal of the american chemical society,132(4),1377-1382.
MLA	He, Youjun,et al."Indene-c-60 bisadduct: a new acceptor for high-performance polymer solar cells".Journal of the american chemical society 132.4(2010):1377-1382.

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