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Morphology and wettability of [bmim][pf6] ionic liquid on hopg substrate
Zhang Fu-Chun1,3; Sha Mao-Lin2; Ren Xiu-Ping1,3; Wu Guo-Zhong1; Hu Jun1; Zhang Yi1
刊名Chinese physics letters
2010-08-01
卷号27期号:8页码:4
ISSN号0256-307X
DOI10.1088/0256-307x/27/8/086101
通讯作者Zhang fu-chun()
英文摘要We investigate the morphology and wettability of [bmim][pf6] ionic liquid (il) on a highly oriented pyrolitic graphite (hopg) substrate using atomic force microscopy. thin films, nanometer-sized droplets, and "drop-on-layer" structures of the il are found on the substrate. films with a thickness of up to 2 nm (about 4 il layers) show the solid-like behavior. in contrast, a dewetting phenomenon is observed for thicker il films, indicating that the il films retain liquid properties. the contact angle of a buck il droplet on the hopg is measured to be about 35 degrees. the wettability of the bulk il droplet on the hopg is found to be quite different from that of il films. these results indicate that the il molecules can be organized into various micro-morphologies when they are confined to a solid substrate and show characteristic behavior at nanometer scales.
WOS关键词SENSITIZED SOLAR-CELLS ; X-RAY REFLECTIVITY ; ROOM-TEMPERATURE ; DOUBLE-LAYER ; MOLECULAR COMPOSITION ; SURFACE ; INTERFACE ; ORIENTATION ; ELECTROLYTE ; SPECTROSCOPY
WOS研究方向Physics
WOS类目Physics, Multidisciplinary
语种英语
出版者IOP PUBLISHING LTD
WOS记录号WOS:000280577200034
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2405748
专题中国科学院大学
通讯作者Zhang Fu-Chun
作者单位1.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China
2.Hefei Normal Univ, Dept Chem & Chem Engn, Hefei 230061, Peoples R China
3.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Zhang Fu-Chun,Sha Mao-Lin,Ren Xiu-Ping,et al. Morphology and wettability of [bmim][pf6] ionic liquid on hopg substrate[J]. Chinese physics letters,2010,27(8):4.
APA Zhang Fu-Chun,Sha Mao-Lin,Ren Xiu-Ping,Wu Guo-Zhong,Hu Jun,&Zhang Yi.(2010).Morphology and wettability of [bmim][pf6] ionic liquid on hopg substrate.Chinese physics letters,27(8),4.
MLA Zhang Fu-Chun,et al."Morphology and wettability of [bmim][pf6] ionic liquid on hopg substrate".Chinese physics letters 27.8(2010):4.
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