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	Lanthanide (iii) addition of [mo2o3s(hnta)(2)](2-) (ln = eu, dy)
	Dang, Zhen-Hua1,2; Mou, Si1; Xu, Li1
刊名	Journal of solid state chemistry
	2009-10-01
卷号	182期号:10页码:2840-2845
关键词	Molybdenum Lanthanide Heterometallic cluster Hydrogen bond Crystal structure Supramolecular
ISSN号	0022-4596
DOI	10.1016/j.jssc.2009.07.051
通讯作者	Xu, li(xli@fjirsm.ac.cn)
英文摘要	The reactions of lncl(3)center dot 6h(2)o (ln = eu or dy) and na-2[mo2o3s(hnta)(2)]center dot 6h(2)o afford na[mo2o3s(hnta)(2)](2)center dot eu(h2o)(9)center dot 3h(2)o (1) (nta = nitrilotriacetate) and na{(h2o)(6)dy[mo2o3s(hnta)(2)](2)}center dot 7.5h(2)o (2), respectively. the [mo2o3s(hnta)(2)](2-) cluster units of 1 are interconnected by na+ into a 3-d open framework with rutile topology templated by eu(h2o)(9)(3+). the coordination of [mo2o3s(hnta)(2)](2-) to the slightly smaller dy3+ ion of greater ionic potential as a consequence of lanthanide contraction has been observed to form the pentanuclear heterometallic {dy(h2o)(6)[mo2o3s(hnta)(2)](2)}(-), which is linked by na+ and hydrogen bonds between the protonated carboxylate groups into a 3-d supramolecular framework. the weak antiferromagnetic interactions between the dy3+ ions of 2 have been observed. (c) 2009 elsevier inc. all rights reserved.
WOS关键词	MOLYBDENUM(V) ; COMPLEXES ; CRYSTAL ; RUTILE
WOS研究方向	Chemistry
WOS类目	Chemistry, Inorganic & Nuclear ; Chemistry, Physical
语种	英语
出版者	ACADEMIC PRESS INC ELSEVIER SCIENCE
WOS记录号	WOS:000270747800037
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2401318
专题	中国科学院大学
通讯作者	Xu, Li
作者单位	1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式 GB/T 7714	Dang, Zhen-Hua,Mou, Si,Xu, Li. Lanthanide (iii) addition of [mo2o3s(hnta)(2)](2-) (ln = eu, dy)[J]. Journal of solid state chemistry,2009,182(10):2840-2845.
APA	Dang, Zhen-Hua,Mou, Si,&Xu, Li.(2009).Lanthanide (iii) addition of [mo2o3s(hnta)(2)](2-) (ln = eu, dy).Journal of solid state chemistry,182(10),2840-2845.
MLA	Dang, Zhen-Hua,et al."Lanthanide (iii) addition of [mo2o3s(hnta)(2)](2-) (ln = eu, dy)".Journal of solid state chemistry 182.10(2009):2840-2845.

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