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	Synthesis, characterization, and properties of a new thioantimonate(iii), [c5n2h16]sb8s13 center dot h2o
	Wang, Xin1,2; Sheng, Tian-Lu1; Chen, Jian-Shan1; Hu, Sheng-Min1; Fu, Rui-Biao1; Wu, Xin-Tao1
刊名	Journal of molecular structure
	2009-11-12
卷号	936期号:1-3页码:142-146
关键词	Thioantimonate(iii) Crystal structure Thermoanalysis Semiconductor Impedance Bulk and grain conductivity
ISSN号	0022-2860
DOI	10.1016/j.molstruc.2009.07.029
通讯作者	Wu, xin-tao(wxt@fjirsm.ac.cn)
英文摘要	A new thioantimonate(iii) with the 2d anionic framework, [3-depnh(2)]sb8s13 center dot h2o 1 (3-depn = 3-dimethylpropanediamine), has been synthesized under solvothermal reactions and characterized by single-crystal x-ray diffraction analysis, ir, elemental analysis, eds, and x-ray powder diffraction. in the 2d porous (sb8s132-)n layer of compound 1, there are two different coordination modes for sb atoms. 1 is a semiconductor with the band gap of e-g = 1.97 ev (629 nm). the thermogravimetric analysis is also discussed. moreover, the impedance spectroscopic measurements of 1 reveal that the bulk conductivity is 5.68 x 10(-6) s cm(-1), and the grain boundary conductivity is 1.43 x 10(-6) s cm(-1). (c) 2009 elsevier b.v. all rights reserved.
WOS关键词	CRYSTAL-STRUCTURES ; SOLVOTHERMAL SYNTHESIS ; THERMAL-STABILITY ; ANTIMONY SULFIDES ; COMPLEXES ; CLUSTERS ; SN
WOS研究方向	Chemistry
WOS类目	Chemistry, Physical
语种	英语
出版者	ELSEVIER SCIENCE BV
WOS记录号	WOS:000273349000023
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2398689
专题	中国科学院大学
通讯作者	Wu, Xin-Tao
作者单位	1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China
推荐引用方式 GB/T 7714	Wang, Xin,Sheng, Tian-Lu,Chen, Jian-Shan,et al. Synthesis, characterization, and properties of a new thioantimonate(iii), [c5n2h16]sb8s13 center dot h2o[J]. Journal of molecular structure,2009,936(1-3):142-146.
APA	Wang, Xin,Sheng, Tian-Lu,Chen, Jian-Shan,Hu, Sheng-Min,Fu, Rui-Biao,&Wu, Xin-Tao.(2009).Synthesis, characterization, and properties of a new thioantimonate(iii), [c5n2h16]sb8s13 center dot h2o.Journal of molecular structure,936(1-3),142-146.
MLA	Wang, Xin,et al."Synthesis, characterization, and properties of a new thioantimonate(iii), [c5n2h16]sb8s13 center dot h2o".Journal of molecular structure 936.1-3(2009):142-146.

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