Synthesis and characterization of life(0.9)mg(0.1)po(4)/nano-carbon webs composite cathode | |
Liu, Hui1,2; Xie, Jingying1 | |
刊名 | Journal of materials processing technology
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2009 | |
卷号 | 209期号:1页码:477-481 |
关键词 | Lifepo(4) Composite cathode Doping Nano-carbon webs Li-ion batteries |
ISSN号 | 0924-0136 |
DOI | 10.1016/j.jmatprotec.2008.02.014 |
通讯作者 | Xie, jingying(jyxie@mail.sim.ac.cn) |
英文摘要 | Life(0.9)mg(0.1)po(4)/nano-carbon webs composite cathode material was synthesized from nanocrystalline fe(3)o(4) through sol-gel process, followed by carbothermal reduction reaction in the presence of lioh center dot h(2)o and nh(4)h(2)po(4). sucrose molecule was introduced through liquid phase and used to construct carbon webs structure. fe-sem and hr-tem observations show that decomposed carbon can form typical carbon webs structure to connect and wrap life(0.9)mg(0.1)po(4) particles. electrochemical tests indicated that the mg-doping at 4c site of carbon-coated lifepo(4) did not affect the olivine structure of the lithium iron phosphate but obviously improve its discharge capacity and rate capability, which would be ascribed to the increased electronic conductivity and/or the mobility of li(+) ion induced by the doping method. (c) 2008 elsevier b.v. all rights reserved. |
WOS关键词 | LI-ION BATTERIES ; PHOSPHO-OLIVINES ; LIFEPO4 ; PERFORMANCE ; CONDUCTIVITY ; ELECTRODES |
WOS研究方向 | Engineering ; Materials Science |
WOS类目 | Engineering, Industrial ; Engineering, Manufacturing ; Materials Science, Multidisciplinary |
语种 | 英语 |
出版者 | ELSEVIER SCIENCE SA |
WOS记录号 | WOS:000261256000059 |
内容类型 | 期刊论文 |
URI标识 | http://www.corc.org.cn/handle/1471x/2397136 |
专题 | 中国科学院大学 |
通讯作者 | Xie, Jingying |
作者单位 | 1.Chinese Acad Sci, Shanghai Inst Microsyst & Informat Technol, Energy Sci & Technol Lab, Shanghai 200050, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Liu, Hui,Xie, Jingying. Synthesis and characterization of life(0.9)mg(0.1)po(4)/nano-carbon webs composite cathode[J]. Journal of materials processing technology,2009,209(1):477-481. |
APA | Liu, Hui,&Xie, Jingying.(2009).Synthesis and characterization of life(0.9)mg(0.1)po(4)/nano-carbon webs composite cathode.Journal of materials processing technology,209(1),477-481. |
MLA | Liu, Hui,et al."Synthesis and characterization of life(0.9)mg(0.1)po(4)/nano-carbon webs composite cathode".Journal of materials processing technology 209.1(2009):477-481. |
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